Vladimir, Vladimir, Russian Federation
Vladimir, Vladimir, Russian Federation
The paper presents a comprehensive study of an innovative technology for producing unoxidised bitumen based on the double cracking (2K) method of petroleum residues (tar, fuel oil). The authors compare 2K bitumen with oxidised bitumen of the BND grade (GOST 33133–2014). A detailed analysis of the molecular structure of traditional and modified bitumens revealed the instability of the latter, where polymer additives only temporarily support the natural structure. Unlike traditional bitumens, unoxidised bitumen obtained by double cracking is characterised by an optimal ratio of asphaltenes and maltenes. This determines its operational properties, which are valuable for road construction. The paper describes in detail the stages of the double cracking process and presents the material balance. The authors also formulated requirements for the quality of unoxidised bitumen for road construction. A significant socio-economic effect is achieved by increasing the durability of road surfaces and reducing the costs of their maintenance.
bitumen, cracking, tar, fuel oil, highways, roadbed
1. Yakontseva, O.V. and Shchepeteva, L.S. (2020), ''Influence of the grain size distribution of asphalt concrete on the physical and mechanical properties'', Transport. Transport structures. Ecology, no. 3, pp. 71-76. DOI: https://doi.org/10.15593/24111678/2020.03.09 (in Russian). EDN: https://elibrary.ru/QPIYOL
2. Belyaev, P.S., Polushkin, D.L., Makeev, P.V. and Frolov, V.A. (2016), ''Modification of petroleum road bitumen with polymer materials to obtain asphalt concrete pavements with improved performance characteristics'', Bull. TSTU, vol. 22, no. 2, pp. 264-271 (in Russian). DOI: https://doi.org/10.17277/vestnik.2016.02.pp.264-271; EDN: https://elibrary.ru/VWDSXH
3. Solomentsev, A.B. and Kulikova, A.V. (2015), ''Functional Values of Polymer Additives'', Automobile Roads, vol. 1, pp. 64-69 (in Russian).
4. Provatorova, G.V. and Vikhrev, A.V. (2021), ''Modification of Bitumen for Road Construction'', Inter. Sci. and Techn. Conf. MPCPE: Inter. Conf. on Mat. Phys., Build. Struct. and Technol. in Constr., Industr. and Prod. Eng. DOI: https://doi.org/10.1088/1757-899X/896/1/012088
5. Fokin, M.D., Vikhrev, A.V., Kandrashkina, Yu.S. and Ilyichev, D.A. (2024), ''Prospects of Using Unoxidized Bitumens in Road Construction'', Inter. Conf. Mat. Phys., Build. Struct. and Technol. in Constr., Industr. and Prod. Eng. (MPCPE-2024): Coll. Proc. of the V Inter. Sci. and Techn. Conf. April 23-25. 2024, Vladimir, Vladimir State Univer. named after A.G. and N.G. Stoletov. Vladimir: Arkaim, pp. 237-242 (in Russian). EDN: https://elibrary.ru/HVVLHD
6. Pat. 2645338 Russia. Method for Thermal Cracking of Organic Polymer Waste / Kryuchkov, V.A.; publ. 09.12.2016.
7. Vikhrev, A.V. and Fokin, M.D. (2024), ''Pilot-industrial unit for producing unoxidized bitumen'', Sci. Days of Students of Vladimir State University named after Alexander Grigorievich and Nikolai Grigorievich Stoletov: Coll. Mat. Sci. Pract. Conf. Vladimir: VlSU, pp. 955-961 (in Russian).
8. Pat. 2761921 Russia. Method for Obtaining a Multifunctional Nanodispersed Catalytic System Based on Native Metal Chelate Complexes under Thermolysis Conditions of Hydrocarbon Feedstock / Petukhov, R.V. and Korolev, D.S.; publ. 14.12.2021.
9. Elsufiev, K.A., Muravyova, Ya.I. and Vdovikh, P.E. (2017), ''Nelder-Mead Optimization Method'', Breakthrough Sci. Res.: Problems, Patterns, Prospects: Coll. of Articles from the IX Inter. Sci. Pract. Conf.: in 4 parts. Penza, December 30, Part 1. Penza: “Science and Enlightenment” (IP Gulyaev G.Yu.), pp. 113-116 (in Russian). EDN: https://elibrary.ru/YKVIHY
10. Yongchun, Cheng, Di, Yu, Guojin, Tan and Chunfeng, Zhu (2018), ''Low-Temperature Performance and Damage Constitutive Model of Eco-Friendly Basalt Fiber – Diatomite – Modified Asphalt Mixture under Freeze-Thaw Cycles'', Art. (PDF Available), Materials, vol. 11, no. 11, p. 1148. DOI: https://doi.org/10.3390/ma11112148.
11. Yafeng, Gong, Haipeng, Bi, Zhenhong, Tian and Guojin, Tan (2018), ''Pavement Performance Investigation of Nano-TiO2/CaCO3 and Basalt Fiber Composite Modified Asphalt Mixture under Freeze-Thaw Cycles'', Appl. Sci., vol. 8, no. 12, p. 2581. DOI: https://doi.org/10.3390/app8122581.



