Ярославль, Ярославская область, Россия
Ярославль, Ярославская область, Россия
Исследовано нитрование 4-хлор-3-нитробензойной кислоты. Субстрат является сильно дезактивированным для реакций SEAr, и требуются жесткие условия для их проведения (безводный KNO3 в концентрированной H2SO4 при 165 °С в течение 10 часов). Разработаны методики превращения 4-хлор-3,5-динитробензойной кислоты и её сложного эфира в новые полициклические системы, содержащие пиридиновый или пиперидиновый фрагменты в реакциях кватернизации и восстановления.
4-хлор-3-нитробензойная кислота, соли N-(2,6-динитроарил)-пиридиния, N-(2,6-динитроарил)-пиперидины, нитрование, кватернизация пиридина
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