Krasnoyarsk V.F. Voino‐Yasenetsky State Medical University
Krasnoyarsk, Krasnoyarsk, Russian Federation
Krasnoyarsk, Krasnoyarsk, Russian Federation
graduate student
Federal'naya territoriya «Sirius», Krasnodar, Russian Federation
from 01.01.2023 until now
Krasnoyarsk, Russian Federation
student
Krasnoyarsk, Krasnoyarsk, Russian Federation
Krasnoyarsk, Russian Federation
V rabote issleduetsya stroenie i fiziko-himicheskie svoystva nitrozopirazolov s perftoralkil'nymi zamestitelyami. Osoboe vnimanie udelyaetsya vliyaniyu atomov ftora na fiziko-himicheskie svoystva soedineniy i ih kislotnost'. Suschestvovanie dimera 4-nitrozopirazolov podtverzhdaetsya IK-spektroskopiey. Pri ustanovlenii stroeniya fragmentacionnyh ionov mass-spektra bylo predpolozheno, chto raspad soedineniy soprovozhdaetsya aziridinovoy peregruppirovkoy. Opredelenie pKa dlya sintezirovannyh gidroksiimino-β-diketonov i nitrozopirazolov provodili spektrofotometricheskim metodom. Opticheskuyu plotnost' rastvorov opredelyali na spektrofotometre. Konstantu kislotnosti opredelyali graficheskim i analiticheskim metodami.
nitrozosoedineniya; konstanta kislotnosti; YaMR-spektroskopiya; hromato-mass-spektrometriya; perftoralkil'nye zamestiteli
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