Abstract (English):
The review deals with literature and own experimental data for synthesis, structural features, spectral, acid-basic and coordinating properties of aromatic macroheterocycles – corroles. Perspectives of practical application of these compounds are considered briefly. Relationship between corrole properties and its geometrical and π-electronic structure is demonstrated. It is shown that corroles have number of features and unique characteristics in despite of insignificant change of structure compared to the most studied class of macroheterocyclic compounds – porphyrins.

Keywords:
tetrapyrrolic macroheterocyclic compounds; porphyrins; corroles; synthesis; spectral characteristics; acid-basic and coordinating properties; metallocomplexes; catalysis; photodynamic therapy

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