OBTAINING A GEOPOLYMER HYBRID BINDER BASED ON THERMAL ENERGY AND METALLURGY BY-PRODUCTS
Abstract and keywords
Abstract (English):
Nowadays, one of the significant issues for the construction industry is the shortage of materials due to the increased volume of work, as well as their rising cost due to the recently imposed anti-Russian restrictions. The most dynamically increasing in price and the most required material in construction at the moment is Portland cement binder. Portland cement production is responsible for more than 7% of the world's carbon dioxide emissions and is a constant source of environmental concern in the neighbouring areas. The solution to these issues could be the creation of a geopolymer binder of hybrid composition from secondary materials of the metallurgical and heat and power industries by their alkaline activation. The purpose of the study was to assess the degree of influence of each mixture component, its content and curing conditions on the mechanical properties of the resulting binder. The results of the study show the possibility of obtaining the required strength values without heat and humidity treatment during the gaining of strength, which allows the hybrid binder to be regarded as an analogue of Portland cement.

Keywords:
construction, roads, binder, geopolymers, fly ash, blast furnace slag, Portland cement
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References

1. Vojtko, A.R., Legkota, E.V. & CHenskaya, A.M. (2022) Severe recession and territorial polarization of investments, Molodoj uchyonyj goda 2022: sbornik statej II Mezhdunarodnogo nauchno-issledovatel'skogo konkursa, Penza, 25 maya 2022 g. Penza, pp. 75–78 (in Russian).

2. Iguminova, V.A. & Rekhovskaya, E.O. (2021) Recycling of waste from TPP plants, Materialy XIX Vserossijskoj nauchno-prakticheskoj konferencii, Omsk, 9–11 nov. 2021 g. Omsk: Omskij gos. tekhn. un-t, pp. 84-87 (in Russian).

3. Fomina, E.V. & Fransishko De Kastro, B.K. (2020) Ecological aspects of the use of steelmaking slag, Racional'noe ispol'zovanie prirodnyh resursov i pererabotka tekhnogennogo syr'ya: fundamental'nye problemy nauki, materialovedenie, himiya i biotekhnologiya, Alushta-Belgorod, 1-5 iunya 2020 g. Belgorod, pp. 290–295 (in Russian).

4. Eroshkina, N.A., Tymchuk, E.I. & Korovkin, M.O. (2015) Structure formation of geopolymers, Molodoj uchenyj, 87, pp. 123–126 (in Russian).

5. Davidovits, J. (1991) Geopolymers - Inorganic polymeric new materials, J. Therm. Anal., 37(8), pp. 1633–1656.

6. Singh, N.B. (2018) Fly ash-based geopolymer binder: A future construction material, Minerals, 8(7), p. 299. DOI:https://doi.org/10.3390/min8070299.

7. John, S.K., Nadir, Y. & Girija, K. (2021). Effect of source materials, additives on the mechanical properties and durability of fly ash and fly ash-slag geopolymer mortar: A review, Construction and Building Materials, 280, pp. 1-32. DOI:https://doi.org/10.1016/j.conbuildmat.2021.122443.

8. Kaya, M. et al. (2022) Influence of micro Fe2O3 and MgO on the physical and mechanical properties of the zeolite and kaolin based geopolymer mortar, J. Build. Eng., 52, pp. 104-443. DOI: https://doi.org/10.1016/j.jobe.2022.104443.

9. Ma, B. et al. (2022) The influence of calcium hydroxide on the performance of MK-based geopolymer, Construction and Building Materials, 329, pp. 127-224. DOI:https://doi.org/10.1016/j.conbuildmat.2022.127224.

10. Liew, Y.M. et al. (2016) Structure and properties of clay-based geopolymer cements: A review, Prog. Mater. Sci., 83, pp. 595–629. DOI: https://doi.org/10.1016/j.pmatsci.2016.08.002.

11. Lekshmi, S. & Sudhakumar, J. (2022) An assessment on the durability performance of fly ash-clay based geopolymer mortar containing clay enhanced with lime and GGBS, Clean. Mater., 5, pp. 100-129. DOI:https://doi.org/10.1016/j.clema.2022.100129.

12. Tekin, I. (2016) Properties of NaOH activated geopolymer with marble, travertine and volcanic tuff wastes, Construction and Building Materials, 127, pp. 607–617. DOI:https://doi.org/10.1016/j.conbuildmat.2016.10.038.

13. Liu, M. et al. (2022) Reusing recycled powder as eco-friendly binder for sustainable GGBS-based geopolymer considering the effects of recycled powder type and replacement rate, J. Clean. Prod., 364, pp. 132656. DOI:https://doi.org/10.1016/j.jclepro.2022.132656.

14. Eroshkina, N.A., Korovkin, M.O. & Korovchenko, I.V. (2015) Technology for obtaining geopolymer binder based on igneous rocks, Molodoj uchenyj, 87, pp. 120–123 (in Russian).

15. Wu, X., Shen, Y. & Hu, L. (2022) Performance of geopolymer concrete activated by sodium silicate and silica fume activator, Case Stud. Constr. Mater., 17, pp. 501-513. DOI: https://doi.org/10.1016/j.cscm.2022.e01513.

16. Petrus, H.T.B.M. et al. (2021) Green geopolymer cement with dry activator from geothermal sludge and sodium hydroxide, J. Clean. Prod., 293, pp. 126-143. DOI: https://doi.org/10.1016/j.jclepro.2021.126143.

17. Pu, S. et al. (2022) Water resistance of fly ash phosphoric acid-based geopolymer, Dev. Built Environ., 12, pp. 1-14. DOI: https://doi.org/10.1016/j.dibe.2022.100093.

18. Yusuf, G. Adewuyi. (2021) Recent Advances in Fly-Ash-Based Geopolymers: Potential on the Utilization for Sustainable Environmental Remediation, ACS Omega, 6(24), pp. 15532–15542. DOI: https://doi.org/10.1021/acsomega.1c00662.

19. Efremov, A.N., Haustova, V.V. & Bukina, D.Yu. (2018) Composite slag-alkaline binders based on sodium hydroxide, blast furnace granulated slag and ash and slag waste from thermal power plants, Vestnik Donbasskoj nacional'noj akademii stroitel'stva i arhitektury, 4-2(132), pp. 177–182 (in Russian).

20. San Nicolas, R.V.R., Walkley, B. & van Deventer, J.S.J. (2017) Fly ash-based geopolymer chemistry and behavior, Coal Combustion Products (CCPs): Characteristics, Utilization and Beneficiation, pp. 185–214. DOI: https://doi.org/10.1016/B978-0-08-100945-1.00007-1.

21. Wongpa, J. et al. (2010) Compressive strength, modulus of elasticity, and water permeability of inorganic polymer concrete, Mater. Des., 31(10), pp. 4748–4754. DOI:https://doi.org/10.1016/j.matdes.2010.05.012.

22. Diaz, E.I., Allouche, E.N. & Eklund, S. (2010) Factors affecting the suitability of fly ash as source material for geopolymers, Fuel, 89(5), pp. 992–996. DOI:https://doi.org/10.1016/j.fuel.2009.09.012.

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