Yaroslavl, Yaroslavl, Russian Federation
Yaroslavl, Yaroslavl, Russian Federation
Yaroslavl, Yaroslavl, Russian Federation
Yaroslavl State Technical University
Yaroslavl, Russian Federation
Yaroslavl, Yaroslavl, Russian Federation
graduate student
Yaroslavl, Yaroslavl, Russian Federation
VAK Russia 1.4.7
VAK Russia 2.6.13
VAK Russia 1.4.3
UDC 547.525.1
UDC 547.572.1
V nastoyaschey rabote alkilirovaniem benzola geksanolom-1 sintezirovana smes', sostoyaschaya iz 60-65% 2-fenilgeksana i 35-40% 3 fenilgeksana. Issledovan perspektivnyy, no maloizuchennyy process aerobnogo zhidkofaznogo okisleniya dannoy smesi do sootvetstvuyuschih gidroperoksidov s cel'yu dal'neyshego polucheniya vysshih ketonov. Ustanovleno, chto ispol'zovanie na etoy stadii N gidroksiftalimida pozvolyaet dostich' tehnologicheskih pokazateley, priemlemyh dlya promyshlennoy realizacii. Tak, konversiya smesi fenilgeksanov sostavlyaet bolee 30% za 60 minut reakcii pri vysokoy selektivnosti obrazovaniya gidroperoksidov.
Alkilirovanie, okislenie, 2-fenilgeksan, 3-fenilgeksan
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