Ярославский государственный университет им. П.Г. Демидова (Доцент)
Ярославль, Ярославская область, Россия
с 01.01.2025 по настоящее время
Ярославский государственный университет им. П.Г. Демидова (Студент)
Ярославль, Ярославская область, Россия
Ярославль, Ярославская область, Россия
The paper investigates the HCl concentration impact on the main and by-processes during the reduction of 1-(2-nitroaryl)-1H-benzotriazole by tin (II) chloride in acidic aqueous-alcoholic medium. The authors have observed the formation of azoxy compounds in addition to the target amino derivative at low HCl content in the reaction mass. The use of 36% hydrochloric acid causes the alkylation of the formed amino compound with alcohol as a solvent.
reduction, condensation, alkylation, 1-(2-aminoaryl)-1H-benzotriazoles, azoxybenzene, alkylamines
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