Sorption of heavy metal ions from aqueous solutions by cellulose sorbent agent

Tatyana Nokoforova; Daria Vokurova

doi:10.52957/27821900_2022_01_08

UDC 544.7

SORPTION OF HEAVY METAL IONS FROM AQUEOUS SOLUTIONS BY CELLULOSE SORBENT AGENT Sorption of heavy metal ions from aqueous solutions by cellulose sorbent agent

АА Аа

Published in From Chemistry Towards Technology Step-By-Step · Volume 3, Issue 1 · Pages 8–20 · Rubric: Scientific articles

DOI: https://doi.org/10.52957/27821900_2022_01_08

Received: 06.12.2021 Accepted: 21.03.2022 Published: 23.03.2022

Authors

Tatyana Nokoforova

Daria Vokurova

Tatyana Nokoforova

Academic degree: doctor of chemical sciences

Science rang: docent

Ivanovo State University of Chemistry and Technology Associate Professor · Ivanovo

Daria Vokurova

Ivanovo State University of Chemistry and Technology Ivanovo

ABSTRACT

The paper concerns the sorption of heavy metal ions from aqueous solutions by cellulose sorbents agents. We modified the wood cellulose by polyvinylpyrrolidone and carboxylic acids. Also we studied the equilibrium and kinetics of Cu(II), Co(II) and Ni(II) ions sorption from aqueous solutions by native and modified cellulose samples. We treated the sorption isotherms under study according to Langmuir models and theory for volume filling of micropores. The Langmuir model is the most correct one for description of the process of heavy metal ions sorption by cellulose sorbents agents. According to the study, the maximum sorption capacity of the modified sorbents is 1.5-2 times higher than the maximum sorption capacity of the native cellulose. The samples obtained can be arranged in the following order of increasing ultimate sorption capacity (A∞): native cellulose < polyvinylpyrrolidone-modified pulp < citric acid-modified pulp. In addition, we studied the influence of media acidity on the sorption of heavy metal ions in pH 1-7. We observed a significant increase in the pH of the initial solution from 1 to 6; there is a rapid increase of the degree of extraction of Cu(II), Cu(II) and Ni(II) ions. Experimentally we obtained the IR spectra of native wood cellulose and its samples modified by polyvinylpyrrolidone and citric acid. Also the authors made an elemental analysis of all types of modified sorbents.

KEYWORDS

cellulose, modification, heavy metal ions, isotherms, sorption kinetics

Funding

The study was carried out using the resources of the Center for Shared Use of Scientific Equipment of the ISUCT (with the support of the Ministry of Science and Higher Education of Russia, grant No. 075-15-2021-671). This work was funded by the Ministry of Science and Higher Education of the Russian Federation (Project No. FZZW–2020–0010).

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GOST

Nokoforova T. E., Vokurova D. A. Sorption of heavy metal ions from aqueous solutions by cellulose sorbent agent // From Chemistry Towards Technology Step-By-Step. 2024. no. 1. pp. 8-20. DOI: https://doi.org/10.52957/27821900_2022_01_08. (Date of access 22.09.2026).

MLA

Tatyana Nokoforova, Vokurova D. A.. "Sorption of heavy metal ions from aqueous solutions by cellulose sorbent agent." From Chemistry Towards Technology Step-By-Step 3.1 (2024): 8-20. DOI: https://doi.org/10.52957/27821900_2022_01_08.

APA

Nokoforova T. E., Vokurova D. A. (2024). Sorption of heavy metal ions from aqueous solutions by cellulose sorbent agent. From Chemistry Towards Technology Step-By-Step, 3(1), 8-20. https://doi.org/10.52957/27821900_2022_01_08

Chicago

Tatyana Nokoforova, Vokurova D. A.. "Sorption of heavy metal ions from aqueous solutions by cellulose sorbent agent." From Chemistry Towards Technology Step-By-Step 3, no. 1 (2024): 8-20. https://doi.org/10.52957/27821900_2022_01_08.

WIKI

{{cite journal | author = Nokoforova T. E., Vokurova D. A. | title = Sorption of heavy metal ions from aqueous solutions by cellulose sorbent agent | journal = From Chemistry Towards Technology Step-By-Step | year = 2024 | volume = 3 | issue = 1 | pages = 8-20 | doi = 10.52957/27821900_2022_01_08 }}

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SORPTION OF HEAVY METAL IONS FROM AQUEOUS SOLUTIONS BY CELLULOSE SORBENT AGENT Sorption of heavy metal ions from aqueous solutions by cellulose sorbent agent

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