Adsorption treatment of wastewater from petroleum products with plasma treated vermiculite

Grigory Gusev; Andrey Gushchin; Vladimir I. Grinevich; Ekaterina Baburina; Tatiana V. Izvekova

doi:10.52957/27821900_2022_02_56

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ADSORPTION TREATMENT OF WASTEWATER FROM PETROLEUM PRODUCTS WITH PLASMA TREATED VERMICULITE Adsorption treatment of wastewater from petroleum products with plasma treated vermiculite

АА Аа

Published in From Chemistry Towards Technology Step-By-Step · Volume 3, Issue 2 · Pages 115–128 · Rubric: Scientific articles

DOI: https://doi.org/10.52957/27821900_2022_02_56

Received: 25.05.2022 Accepted: 17.06.2022 Published: 23.06.2022

Authors

Grigory Gusev

Andrey Gushchin

Vladimir I. Grinevich

Ekaterina Baburina

et al.

Tatiana V. Izvekova

Grigory Gusev

Academic degree: candidate of chemical sciences

Ivanovo State University of Chemistry and Technology Senior Lecturer · Ivanovo

Andrey Gushchin

Academic degree: candidate of chemical sciences

Ivanovo State University of Chemistry and Technology Associate Professor · Ivanovo

Vladimir I. Grinevich

Academic degree: doctor of chemical sciences

Ivanovskiy gosudarstvennyy himiko-tehnologicheskiy universitet professor · Russian Federation · Иваново

Ekaterina Baburina

Ivanovo State University of Chemistry and Technology Ivanovo

Tatiana V. Izvekova

Academic degree: candidate of chemical sciences

Ivanovo State University of Chemistry and Technology Associate Professor · Ivanovo

ABSTRACT

The paper presents the results of studies of wastewater treatment processes from petroleum products using vermiculite before and after treatment in dielectric barrier discharge plasma. During the experiment we determined the time of reaching equilibrium in the heterophase system "sorbent - aqueous solution of petroleum products", is 30 min. The kinetic sorption curves are processed in first- and second-order linear coordinates. We found that the kinetics of petroleum product sorption by vermiculite is most adequately described by a second-order kinetics model, indicating an ion-exchange adsorption process. The article describes the processes of external and internal mass transfer of petroleum products in the presence of vermiculite obtained under different conditions. When treating the sorption kinetics in Boyd-Adamson coordinates we found that the adsorption process proceeds in an inward diffusion regime. Treatment of the sorbent, after use in the wastewater treatment process, in dielectric barrier discharge plasma leads to a slight decrease of sorption characteristics, but results in its regeneration. We studied the morphology of vermiculite obtained under different conditions. The sample is a micro-heterogeneous material with a particle size of 0.4-0.7 µm. The total pore volume obtained from the linear coordinates of the micropore volumetric filling theory is 0.21 cm3/g. All microphotographs reflect the characteristic morphology of the vermiculite mica packet. The results of the study of the sorption properties evaluated by the method of low-temperature inert gas adsorption made it possible to construct isotherms of adsorption/desorption of liquid nitrogen on the sorbent surface, the BET treatment of which showed that the specific surface area of the sorbent is 7 m2/g.

KEYWORDS

adsorption, vermiculite, petroleum products, water treatment, dielectric barrier discharge plasma

Funding

The work to determine the properties of the adsorbent was performed within the framework of the state research assignment (Theme No. FZZW-2020-0010). This work on adsorbent surface treatment in dielectric barrier discharge plasma was performed within the framework of the RF President's Grant for Governmental Support of Young Russian Scientists - Candidate of Sciences (MK-3784.2022.1.3). The research was performed using the resources of the ISUCT Centre for the Collective Use of Scientific Equipment (supported by the Russian Ministry of Education and Science, Agreement No. 075-15-2021-671).

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GOST

Gusev G. I., Gushchin A. A., Grinevich V. I., Baburina E. M., Izvekova T. V. Adsorption treatment of wastewater from petroleum products with plasma treated vermiculite // From Chemistry Towards Technology Step-By-Step. 2024. no. 2. pp. 115-128. DOI: https://doi.org/10.52957/27821900_2022_02_56. (Date of access 25.10.2026).

MLA

Grigory Gusev, Gushchin A. A., Grinevich V. I., Baburina E. M., Izvekova T. V.. "Adsorption treatment of wastewater from petroleum products with plasma treated vermiculite." From Chemistry Towards Technology Step-By-Step 3.2 (2024): 115-128. DOI: https://doi.org/10.52957/27821900_2022_02_56.

APA

Gusev G. I., Gushchin A. A., Grinevich V. I., Baburina E. M., Izvekova T. V. (2024). Adsorption treatment of wastewater from petroleum products with plasma treated vermiculite. From Chemistry Towards Technology Step-By-Step, 3(2), 115-128. https://doi.org/10.52957/27821900_2022_02_56

Chicago

Grigory Gusev, Gushchin A. A., Grinevich V. I., Baburina E. M., Izvekova T. V.. "Adsorption treatment of wastewater from petroleum products with plasma treated vermiculite." From Chemistry Towards Technology Step-By-Step 3, no. 2 (2024): 115-128. https://doi.org/10.52957/27821900_2022_02_56.

WIKI

{{cite journal | author = Gusev G. I., Gushchin A. A., Grinevich V. I., Baburina E. M., Izvekova T. V. | title = Adsorption treatment of wastewater from petroleum products with plasma treated vermiculite | journal = From Chemistry Towards Technology Step-By-Step | year = 2024 | volume = 3 | issue = 2 | pages = 115-128 | doi = 10.52957/27821900_2022_02_56 }}

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ADSORPTION TREATMENT OF WASTEWATER FROM PETROLEUM PRODUCTS WITH PLASMA TREATED VERMICULITE Adsorption treatment of wastewater from petroleum products with plasma treated vermiculite

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