Effect of chemical modification of cotton cellulose by aminoacetic acid on the sorption of Cu(II) and Fe(II) ions

Tatyana Nokoforova; Vladimir Kozlov; Artemiy Sofronov

doi:10.52957/27821900_2023_01_107

UDC 544.2

EFFECT OF CHEMICAL MODIFICATION OF COTTON CELLULOSE BY AMINOACETIC ACID ON THE SORPTION OF CU(II) AND FE(II) IONS Effect of chemical modification of cotton cellulose by aminoacetic acid on the sorption of Cu(II) and Fe(II) ions

АА Аа

Published in From Chemistry Towards Technology Step-By-Step · Volume 4, Issue 1 · Pages 107–116 · Rubric: Scientific articles

DOI: https://doi.org/10.52957/27821900_2023_01_107

Received: 10.02.2023 Accepted: 21.03.2023 Published: 23.03.2023 Language of publication: ENG

Authors

Tatyana Nokoforova

Vladimir Kozlov

Artemiy Sofronov

Tatyana Nokoforova

Academic degree: doctor of chemical sciences

Science rang: docent

Ivanovo State University of Chemistry and Technology Associate Professor · Ivanovo

Vladimir Kozlov

Academic degree: doctor of chemical sciences

Ivanovo State University of Chemistry and Technology Professor · Ivanovo

Artemiy Sofronov

Ivanovo State University of Chemistry and Technology Ivanovo

ABSTRACT

The paper presents the results of the cotton cellulose modification with glycine. To form dialdehyde-cellulose and its subsequent treatment with aminoacetic acid we conducted the modification through an oxidation stage of cellulose with sodium metoperiodate. We studied the sorption properties of the original and modified cellulose samples in relation to Cu(II) and Fe(II) ions. Bykinetic experiments we found the degree of extraction of copper(II) and iron(II) ions. The modified sample was approximately 25% higher compared to the original one. We obtained the most correct results when processing the kinetic sorption curves within the framework of pseudo-second order kinetics model. We determined the optimum conditions for modifying cotton cellulose to achieve maximum sorption of copper (II) and iron (II) ions and obtained the equilibrium-kinetic characteristics of modified and unmodi-fied cotton cellulose. When studying the sorption equilibrium in the heterophase system "cellulose sorbent - aqueous solution of metal sulfate" we took sorption iso-therms, processed them in the framework of Langmuir mode, and determined the values of the ultimate sorption capacity of the native and modified cellulose. We found the ultimate sorption capacity of the modified sorbent is about 1.5-2 times higher than the ultimate sorption capacity of native cotton cellulose. We have ob-tained IR spectra of native andmodified cellulose samples. Also we have performed elemental analysis and obtained images of the sorption materials surface structure based on cotton cellulose using SEM.

KEYWORDS

cotton cellulose, modification, aminoacetic acid, sorption, ions Cu(II) and Fe(II)

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Editor in chief

Dmitry Berezin

Deputy Editor in Chief

Igor Abramov

abramovig@ystu.ru

Executive secretary

Zhanna Chirkova

chirkovazhv@ystu.ru

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GOST

Nokoforova T. E., Kozlov V. A., Sofronov A. R. Effect of chemical modification of cotton cellulose by aminoacetic acid on the sorption of Cu(II) and Fe(II) ions // From Chemistry Towards Technology Step-By-Step. 2024. no. 1. pp. 107-116. DOI: https://doi.org/10.52957/27821900_2023_01_107. (Date of access 21.09.2026).

MLA

Tatyana Nokoforova, Kozlov V. A., Sofronov A. R.. "Effect of chemical modification of cotton cellulose by aminoacetic acid on the sorption of Cu(II) and Fe(II) ions." From Chemistry Towards Technology Step-By-Step 4.1 (2024): 107-116. DOI: https://doi.org/10.52957/27821900_2023_01_107.

APA

Nokoforova T. E., Kozlov V. A., Sofronov A. R. (2024). Effect of chemical modification of cotton cellulose by aminoacetic acid on the sorption of Cu(II) and Fe(II) ions. From Chemistry Towards Technology Step-By-Step, 4(1), 107-116. https://doi.org/10.52957/27821900_2023_01_107

Chicago

Tatyana Nokoforova, Kozlov V. A., Sofronov A. R.. "Effect of chemical modification of cotton cellulose by aminoacetic acid on the sorption of Cu(II) and Fe(II) ions." From Chemistry Towards Technology Step-By-Step 4, no. 1 (2024): 107-116. https://doi.org/10.52957/27821900_2023_01_107.

WIKI

{{cite journal | author = Nokoforova T. E., Kozlov V. A., Sofronov A. R. | title = Effect of chemical modification of cotton cellulose by aminoacetic acid on the sorption of Cu(II) and Fe(II) ions | journal = From Chemistry Towards Technology Step-By-Step | year = 2024 | volume = 4 | issue = 1 | pages = 107-116 | doi = 10.52957/27821900_2023_01_107 }}

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EFFECT OF CHEMICAL MODIFICATION OF COTTON CELLULOSE BY AMINOACETIC ACID ON THE SORPTION OF CU(II) AND FE(II) IONS Effect of chemical modification of cotton cellulose by aminoacetic acid on the sorption of Cu(II) and Fe(II) ions

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