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From Chemistry Towards Technology Step-By-Step
Journals / From Chemistry Towards Technology Step-By-Step / Volume 4 Issue 1 / Modelling of rubber thermal degradation kinetics during the pyrolysis of rubber waste
UDC
66.092-977

MODELLING OF RUBBER THERMAL DEGRADATION KINETICS DURING THE PYROLYSIS OF RUBBER WASTE Modelling of rubber thermal degradation kinetics during the pyrolysis of rubber waste

Published in From Chemistry Towards Technology Step-By-Step · Pages 70–85 · Rubric: Scientific articles
DOI: https://doi.org/10.52957/27821900_2023_01_70
Received: 12.01.2023 Accepted: 22.03.2023 Published: 23.03.2023
Authors
MI
Mikhail Soloviev
ORCID
VI
Viktor Kablov
ORCID SPIN
SE
Sergey Baldaev
ORCID
MA
Maria Fedorova
ABSTRACT
Primenitel'no k processu piroliza iznoshennyh shin i othodov rezino-tehnicheskih izdeliy v promyshlennom reaktore privedena kineticheskaya model' termodestrukcii polimera. Vypolneny kvantovo-himicheskie raschety izmeneniya termodinamicheskih funkciy pri veroyatnyh himicheskih reakciyah destrukcii setchatyh elastomerov. V kachestve produktov reakcii rassmotrena tverdaya frakciya (tehnicheskiy uglerod i othody metalla) i parogazovaya smes', razdelyaemaya na tri frakcii uglevodorodov. Pri opisanii kinetiki destrukcii rezin ispol'zovana formal'naya kineticheskaya shema, otrazhayuschaya mehanizm processa kak sovokupnost' radikal'no-cepnyh reakciy destrukcii polimera. Kazhdoy frakcii uglevodorodov sootvetstvuet opredelennyy nabor kineticheskih konstant, temperaturnye zavisimosti kotoryh prinyaty arreniusovskimi. Udovletvoritel'noe soglasie poluchennyh raschetnyh termogravimetricheskih zavisimostey s eksperimental'nymi dannymi razlichnyh avtorov pozvolilo approksimirovat' krivye termodestrukcii rezin krivymi, harakterizuyuschimi kauchuki obschego naznacheniya.
KEYWORDS
iznoshennye shiny, rezinovye othody, piroliz, kineticheskaya model', kvantovo-himicheskiy raschet
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