Effect of chemical modification of cotton cellulose by aminoacetic acid on the sorption of Cu(II) and Fe(II) ions

Tatyana Nokoforova; Vladimir Kozlov; Artemiy Sofronov

doi:10.52957/27821900_2023_01_32

UDC 544.7

EFFECT OF CHEMICAL MODIFICATION OF COTTON CELLULOSE BY AMINOACETIC ACID ON THE SORPTION OF CU(II) AND FE(II) IONS Effect of chemical modification of cotton cellulose by aminoacetic acid on the sorption of Cu(II) and Fe(II) ions

АА Аа

Published in From Chemistry Towards Technology Step-By-Step · Volume 4, Issue 1 · Pages 32–42 · Rubric: Scientific articles

DOI: https://doi.org/10.52957/27821900_2023_01_32

Received: 10.02.2023 Accepted: 17.03.2023 Published: 23.03.2023

Authors

Tatyana Nokoforova

Vladimir Kozlov

Artemiy Sofronov

Tatyana Nokoforova

Academic degree: doctor of chemical sciences

Science rang: docent

Ivanovo State University of Chemistry and Technology Associate Professor · Ivanovo

Vladimir Kozlov

Academic degree: doctor of chemical sciences

Ivanovo State University of Chemistry and Technology Professor · Ivanovo

Artemiy Sofronov

Ivanovo State University of Chemistry and Technology Ivanovo

ABSTRACT

Predstavleny rezul'taty modificirovaniya hlopkovoy cellyulozy glicinom. Modificirovanie provodili cherez stadiyu okisleniya cellyulozy metaperiodatom natriya s obrazovaniem dial'degidcellyulozy i ee posleduyuschey obrabotkoy aminouksusnoy kislotoy. Issledovany sorbcionnye svoystva obrazcov ishodnoy i modificirovannoy cellyulozy po otnosheniyu k ionam Cu(II) i Fe(II). V kineticheskih eksperimentah ustanovleno, chto stepen' izvlecheniya ionov medi(II) i zheleza(II) modificirovannym obrazcom primerno na 25% vyshe po sravneniyu s ishodnym. Pri obrabotke kineticheskih krivyh sorbcii v ramkah modeli kinetiki psevdo-vtorogo poryadka polucheny naibolee korrektnye rezul'taty. Opredeleny optimal'nye usloviya modificirovaniya hlopkovoy cellyulozy dlya dostizheniya maksimal'noy sorbcii ionov medi(II) i zheleza(II), polucheny ravnovesno-kineticheskie harakteristiki modificirovannoy i nemodificirovannoy hlopkovoy cellyulozy. Pri izuchenii sorbcionnogo ravnovesiya v geterofaznoy sisteme «cellyuloznyy sorbent – vodnyy rastvor sul'fata metalla» snyaty izotermy sorbcii, provedena ih obrabotka v ramkah modeli Lengmyura i opredeleny velichiny predel'noy sorbcionnoy emkosti nativnoy i modificirovannoy cellyulozy. Ustanovleno, chto predel'naya sorbcionnaya emkost' modificirovannogo sorbenta primerno v 1,5 2 raza prevyshaet predel'nuyu sorbcionnuyu emkost' nativnoy hlopkovoy cellyulozy. Polucheny IK-spektry nativnoy cellyulozy i ee modificirovannogo obrazca. Vypolnen elementnyy analiz i polucheny izobrazheniya poverhnostnoy struktury sorbcionnyh materialov na osnove hlopkovoy cellyulozy s pomosch'yu SEM.

KEYWORDS

hlopkovaya cellyuloza, modificirovanie, aminouksusnaya kislota, sorbciya, iony Cu(II) i Fe(II)

Funding

Issledovanie provedeno s ispol'zovaniem resursov Centra kollektivnogo pol'zovaniya nauchnym oborudovaniem IGHTU (pri podderzhke Minobrnauki Rossii, soglashenie № 075-15-2021-671)

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Editor in chief

Dmitry Berezin

Deputy Editor in Chief

Igor Abramov

abramovig@ystu.ru

Executive secretary

Zhanna Chirkova

chirkovazhv@ystu.ru

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Nokoforova T. E., Kozlov V. A., Sofronov A. R. Effect of chemical modification of cotton cellulose by aminoacetic acid on the sorption of Cu(II) and Fe(II) ions // From Chemistry Towards Technology Step-By-Step. 2024. no. 1. pp. 32-42. DOI: https://doi.org/10.52957/27821900_2023_01_32. (Date of access 22.09.2026).

MLA

Tatyana Nokoforova, Kozlov V. A., Sofronov A. R.. "Effect of chemical modification of cotton cellulose by aminoacetic acid on the sorption of Cu(II) and Fe(II) ions." From Chemistry Towards Technology Step-By-Step 4.1 (2024): 32-42. DOI: https://doi.org/10.52957/27821900_2023_01_32.

APA

Nokoforova T. E., Kozlov V. A., Sofronov A. R. (2024). Effect of chemical modification of cotton cellulose by aminoacetic acid on the sorption of Cu(II) and Fe(II) ions. From Chemistry Towards Technology Step-By-Step, 4(1), 32-42. https://doi.org/10.52957/27821900_2023_01_32

Chicago

Tatyana Nokoforova, Kozlov V. A., Sofronov A. R.. "Effect of chemical modification of cotton cellulose by aminoacetic acid on the sorption of Cu(II) and Fe(II) ions." From Chemistry Towards Technology Step-By-Step 4, no. 1 (2024): 32-42. https://doi.org/10.52957/27821900_2023_01_32.

WIKI

{{cite journal | author = Nokoforova T. E., Kozlov V. A., Sofronov A. R. | title = Effect of chemical modification of cotton cellulose by aminoacetic acid on the sorption of Cu(II) and Fe(II) ions | journal = From Chemistry Towards Technology Step-By-Step | year = 2024 | volume = 4 | issue = 1 | pages = 32-42 | doi = 10.52957/27821900_2023_01_32 }}

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EFFECT OF CHEMICAL MODIFICATION OF COTTON CELLULOSE BY AMINOACETIC ACID ON THE SORPTION OF CU(II) AND FE(II) IONS Effect of chemical modification of cotton cellulose by aminoacetic acid on the sorption of Cu(II) and Fe(II) ions

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