Principles of aerobic oxidation of ethylbenzene to hydroperoxide under the presence of phthalimide catalysts

Ekaterina A. Kurganova; Egor Bayov; Aleksandr Frolov; Viktoriya Kabanova; Georgy Koshel; Aleksandr Petukhov

doi:10.52957/2782-1900-2024-4-2-8-16

UDC 661.71 UDC 547.534.1

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PRINCIPLES OF AEROBIC OXIDATION OF ETHYLBENZENE TO HYDROPEROXIDE UNDER THE PRESENCE OF PHTHALIMIDE CATALYSTS Principles of aerobic oxidation of ethylbenzene to hydroperoxide under the presence of phthalimide catalysts

АА Аа

Published in From Chemistry Towards Technology Step-By-Step · Volume 4, Issue 2 · Pages 8–16 · Rubric: Scientific articles

DOI: https://doi.org/10.52957/2782-1900-2024-4-2-8-16

Received: 03.05.2023 Accepted: 12.05.2023 Published: 23.06.2023

Authors

Ekaterina A. Kurganova

Egor Bayov

Aleksandr Frolov

ORCID Scopus ResearcherID SPIN

Viktoriya Kabanova

et al.

Georgy Koshel

Aleksandr Petukhov

Ekaterina A. Kurganova

Yaroslavl State Technical University Professor · Yaroslavl

Egor Bayov

Yaroslavl State Technical University Yaroslavl

Aleksandr Frolov

Academic degree: candidate of chemical sciences

Yaroslavl State Technical University Associate Professor · kafedra "Himicheskaya tehnologiya veschestv i materialov" · Yaroslavl

ORCID Scopus ResearcherID SPIN

Viktoriya Kabanova

Academic degree: graduate student of chemical sciences

Yaroslavl State Technical University Assistant · Yaroslavl

Yaroslavl State Technical University Yaroslavl

Georgy Koshel

Academic degree: doctor of chemical sciences

Science rang: professor

Yaroslavl State Technical University Professor · Yaroslavl

Aleksandr Petukhov

Academic degree: doctor of chemical sciences

Kazan National Research Technological University Professor · Kazan

ABSTRACT

Issledovany osnovnye zakonomernosti processa aerobnogo zhidkofaznogo okisleniya etilbenzola do gidroperoksida. Ustanovleno, chto primenenie ftalimidnyh katalizatorov (N gidroksiftalimid i ego proizvodnye) pozvolyaet povysit' skorost' okisleniya dannogo uglevodoroda v 1,5-2 raza po sravneniyu s iniciatorami razlichnoy prirody. Pri etom sohranyaetsya vysokaya selektivnost' obrazovaniya celevogo gidroperoksida – okolo 90%. Na osnovanii eksperimental'nyh dannyh rekomendovany usloviya osuschestvleniya reakcii okisleniya etilbenzola v prisutstvii ftalimidnyh katalizatorov. Poluchennye rezul'taty mogut byt' ispol'zovany dlya usovershenstvovaniya tehnologii sovmestnogo proizvodstva oksida propilena i stirola – cennyh produktov osnovnogo organicheskogo i neftehimicheskogo sinteza.

KEYWORDS

etilbenzol, zhidkofaznoe aerobnoe okislenie, gidroperoksid etilbenzola, N-gidroksiftalimid, ftalimidnye katalizatory, oksid propilena, stirol

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GOST

Kurganova E. A., Bayov E. I., Frolov A. S., Kabanova V. S., Koshel G. N., Petukhov A. A. Principles of aerobic oxidation of ethylbenzene to hydroperoxide under the presence of phthalimide catalysts // From Chemistry Towards Technology Step-By-Step. 2024. no. 2. pp. 8-16. DOI: https://doi.org/10.52957/2782-1900-2024-4-2-8-16. (Date of access 24.10.2026).

MLA

Ekaterina A. Kurganova, Bayov E. I., Frolov A. S., Kabanova V. S., Koshel G. N., Petukhov A. A.. "Principles of aerobic oxidation of ethylbenzene to hydroperoxide under the presence of phthalimide catalysts." From Chemistry Towards Technology Step-By-Step 4.2 (2024): 8-16. DOI: https://doi.org/10.52957/2782-1900-2024-4-2-8-16.

APA

Kurganova E. A., Bayov E. I., Frolov A. S., Kabanova V. S., Koshel G. N., Petukhov A. A. (2024). Principles of aerobic oxidation of ethylbenzene to hydroperoxide under the presence of phthalimide catalysts. From Chemistry Towards Technology Step-By-Step, 4(2), 8-16. https://doi.org/10.52957/2782-1900-2024-4-2-8-16

Chicago

Ekaterina A. Kurganova, Bayov E. I., Frolov A. S., Kabanova V. S., Koshel G. N., Petukhov A. A.. "Principles of aerobic oxidation of ethylbenzene to hydroperoxide under the presence of phthalimide catalysts." From Chemistry Towards Technology Step-By-Step 4, no. 2 (2024): 8-16. https://doi.org/10.52957/2782-1900-2024-4-2-8-16.

WIKI

{{cite journal | author = Kurganova E. A., Bayov E. I., Frolov A. S., Kabanova V. S., Koshel G. N., Petukhov A. A. | title = Principles of aerobic oxidation of ethylbenzene to hydroperoxide under the presence of phthalimide catalysts | journal = From Chemistry Towards Technology Step-By-Step | year = 2024 | volume = 4 | issue = 2 | pages = 8-16 | doi = 10.52957/2782-1900-2024-4-2-8-16 }}

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PRINCIPLES OF AEROBIC OXIDATION OF ETHYLBENZENE TO HYDROPEROXIDE UNDER THE PRESENCE OF PHTHALIMIDE CATALYSTS Principles of aerobic oxidation of ethylbenzene to hydroperoxide under the presence of phthalimide catalysts

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