Assessment of polyfunctional macrocyclic compounds in solution by cryoscopic method

Nadezhda Berezina; Egor Kolesov

doi:10.52957/2782-1900-2024-4-3-76-80

UDC 544.032

ASSESSMENT OF POLYFUNCTIONAL MACROCYCLIC COMPOUNDS IN SOLUTION BY CRYOSCOPIC METHOD Assessment of polyfunctional macrocyclic compounds in solution by cryoscopic method

АА Аа

Published in From Chemistry Towards Technology Step-By-Step · Volume 4, Issue 3 · Pages 76–80 · Rubric: Scientific articles

DOI: https://doi.org/10.52957/2782-1900-2024-4-3-76-80

Received: 01.09.2023 Accepted: 08.09.2023 Published: 23.09.2023

Authors

Nadezhda Berezina

Egor Kolesov

Nadezhda Berezina

Academic degree: candidate of chemical sciences

Ivanovo State University of Chemistry and Technology Associate Professor · Ivanovo

Egor Kolesov

Ivanovo State University of Chemistry and Technology Ivanovo

ABSTRACT

The article considers the synthesis of meso-tetrakis(1'-methyl-pyrid-4-yl)porphyrin tetratosylate and meso-tetrakis(1'-methyl-carboxymethylpyrid-4-yl)porphyrin tetrabromide. The authors qualified the porphyrin ligands in terms of the electron and 1H NMR spectroscopy. The research determines the decrease of freezing point (ΔTfr) of aqueous solutions of porphyrins, as well as a model N-methyl-pyridinium salt (1 methyl-pyridinium iodide). We used the obtained experimental values of ΔT3 to determine the isotonic coefficient. The obtained results indicate the compounds are almost completely dissociated in the indicated concentration range in dilute solutions.

KEYWORDS

Water-soluble tetrapyridylporphyrins, water, isotonic coefficient, cryoscopy

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Editor in chief

Dmitry Berezin

Deputy Editor in Chief

Igor Abramov

abramovig@ystu.ru

Executive secretary

Zhanna Chirkova

chirkovazhv@ystu.ru

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GOST

Berezina N. M., Kolesov E. E. Assessment of polyfunctional macrocyclic compounds in solution by cryoscopic method // From Chemistry Towards Technology Step-By-Step. 2024. no. 3. pp. 76-80. DOI: https://doi.org/10.52957/2782-1900-2024-4-3-76-80. (Date of access 29.09.2026).

MLA

Nadezhda Berezina, Kolesov E. E.. "Assessment of polyfunctional macrocyclic compounds in solution by cryoscopic method." From Chemistry Towards Technology Step-By-Step 4.3 (2024): 76-80. DOI: https://doi.org/10.52957/2782-1900-2024-4-3-76-80.

APA

Berezina N. M., Kolesov E. E. (2024). Assessment of polyfunctional macrocyclic compounds in solution by cryoscopic method. From Chemistry Towards Technology Step-By-Step, 4(3), 76-80. https://doi.org/10.52957/2782-1900-2024-4-3-76-80

Chicago

Nadezhda Berezina, Kolesov E. E.. "Assessment of polyfunctional macrocyclic compounds in solution by cryoscopic method." From Chemistry Towards Technology Step-By-Step 4, no. 3 (2024): 76-80. https://doi.org/10.52957/2782-1900-2024-4-3-76-80.

WIKI

{{cite journal | author = Berezina N. M., Kolesov E. E. | title = Assessment of polyfunctional macrocyclic compounds in solution by cryoscopic method | journal = From Chemistry Towards Technology Step-By-Step | year = 2024 | volume = 4 | issue = 3 | pages = 76-80 | doi = 10.52957/2782-1900-2024-4-3-76-80 }}

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ASSESSMENT OF POLYFUNCTIONAL MACROCYCLIC COMPOUNDS IN SOLUTION BY CRYOSCOPIC METHOD Assessment of polyfunctional macrocyclic compounds in solution by cryoscopic method

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