Cu (II) and Fe (II) ion sorption by cotton cellulose modified with diethylenetriamine

Tatyana Nokoforova; Daria Vokurova

doi:10.52957/2782-1900-2024-5-1-48-57

UDC 544.7

CU (II) AND FE (II) ION SORPTION BY COTTON CELLULOSE MODIFIED WITH DIETHYLENETRIAMINE Cu (II) and Fe (II) ion sorption by cotton cellulose modified with diethylenetriamine

АА Аа

Published in From Chemistry Towards Technology Step-By-Step · Volume 5, Issue 1 · Pages 48–57 · Rubric: Scientific articles

DOI: https://doi.org/10.52957/2782-1900-2024-5-1-48-57

Received: 30.01.2024 Accepted: 12.02.2024 Published: 23.03.2024

Authors

Tatyana Nokoforova

Daria Vokurova

Tatyana Nokoforova

Academic degree: doctor of chemical sciences

Science rang: docent

Ivanovo State University of Chemistry and Technology Associate Professor · Ivanovo

Daria Vokurova

Ivanovo State University of Chemistry and Technology Ivanovo

ABSTRACT

The authors have developed new effective sorbent based on chemically modified cotton cellulose. The modification process consists of two stages, including sequential treatment of cellulose with epichlorohydrin and diethylene triamine. The authors present the optimal modification conditions for the obtained sorbent. It allows ones’ to achieve the highest values of sorption capacity for the extraction of iron(II) and copper(II) ions from aqueous solutions. The authors investigated the kinetics and equilibrium of heavy metal ion sorption in the system "cellulose sorbent - aqueous solution of metal sulphate" for original and modified cotton cellulose. Processing of the kinetic experiment results indicates that the kinetics of metal ion sorption is described most correctly in the framework of the pseudo-second-order kinetics model. Isotherms of heavy metal ions sorption clearly indicate the growth of sorption capacity for the modified sorbent in comparison with the original one. Processing of experimental isotherms within the Langmuir model made it possible to determine the values of the maximum sorption capacity (A∞) of original and modified with diethylenetriamine cotton cellulose with respect to Cu(II) and FE(II) ions. It was found that the A∞ of the modified sorbent was about 3 times higher than the ultimate sorption capacity of original cotton cellulose towards iron(II) and Cu(II) IONS. Comparison of IR spectra of the original cellulose samples and cellulose treated with diethylenetriamine indicates the changes that occurred during chemical modification. The paper presents SEM images showing the changes in the surface structure of the modified sorbent compared to the original one.

KEYWORDS

cotton cellulose, modification, diethylene triamine, sorption, ions Cu(II) and Fe(II)

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Dmitry Berezin

Deputy Editor in Chief

Igor Abramov

abramovig@ystu.ru

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Zhanna Chirkova

chirkovazhv@ystu.ru

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Nokoforova T. E., Vokurova D. A. Cu (II) and Fe (II) ion sorption by cotton cellulose modified with diethylenetriamine // From Chemistry Towards Technology Step-By-Step. 2024. no. 1. pp. 48-57. DOI: https://doi.org/10.52957/2782-1900-2024-5-1-48-57. (Date of access 21.09.2026).

MLA

Tatyana Nokoforova, Vokurova D. A.. "Cu (II) and Fe (II) ion sorption by cotton cellulose modified with diethylenetriamine." From Chemistry Towards Technology Step-By-Step 5.1 (2024): 48-57. DOI: https://doi.org/10.52957/2782-1900-2024-5-1-48-57.

APA

Nokoforova T. E., Vokurova D. A. (2024). Cu (II) and Fe (II) ion sorption by cotton cellulose modified with diethylenetriamine. From Chemistry Towards Technology Step-By-Step, 5(1), 48-57. https://doi.org/10.52957/2782-1900-2024-5-1-48-57

Chicago

Tatyana Nokoforova, Vokurova D. A.. "Cu (II) and Fe (II) ion sorption by cotton cellulose modified with diethylenetriamine." From Chemistry Towards Technology Step-By-Step 5, no. 1 (2024): 48-57. https://doi.org/10.52957/2782-1900-2024-5-1-48-57.

WIKI

{{cite journal | author = Nokoforova T. E., Vokurova D. A. | title = Cu (II) and Fe (II) ion sorption by cotton cellulose modified with diethylenetriamine | journal = From Chemistry Towards Technology Step-By-Step | year = 2024 | volume = 5 | issue = 1 | pages = 48-57 | doi = 10.52957/2782-1900-2024-5-1-48-57 }}

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CU (II) AND FE (II) ION SORPTION BY COTTON CELLULOSE MODIFIED WITH DIETHYLENETRIAMINE Cu (II) and Fe (II) ion sorption by cotton cellulose modified with diethylenetriamine

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