APPLYING OF DOMESTIC ALUMINOSILICATE MATERIALS FOR PURIFICATION OF MUSTARD OIL BY SORPTION
Abstract and keywords
Abstract (English):
On the basis of X-ray phase analysis data we identified the main structural elements of the solid phase of domestic aluminosilicates of different colours used for the purification of mustard oil by sorption. Also we defined these materials fractional and particle size distribution and realized 60-80% of their particles are 0.3-2.5 µm in size. The study reveals the important role of rock-forming fractions kaolinite and montmorillonite (up to 15%), high dispersion and moderately alkaline surface (pH of 1% aqueous dispersion  8.40-8.43) of aluminosilicate materials by LLC "PolyServis-M" (Moscow) in oil neutralization and bleaching. By the experiment results introduction of these domestic materials into mustard oil prevents its oxidation.

Keywords:
natural aluminosilicates, purification by sorption, mustard oil, free fatty acids, peroxides and wax compounds
Text
Publication text (PDF): Read Download
References

1. Prokof'ev V.Yu., Razgovorov P.B., Gordina N.E. The adsorption of undesirable impurities from sunflower oil the granulated sorbents based on caolin clay // Int. J. Food Eng. 2014. Vol. 10, no. 4. P. 713-720. DOIhttps://doi.org/10.1515/ijfe-2014-0103.

2. Shapkin N.P., Razov V.I., Khal’chenko I.G., Shkuratov A.L., Korochentsev V.V., Mayorov V.I. Studies of natural kaolinite and its modified forms // J. Inorg. Chem. 2016. Vol. 61, no. 11. P. 1463-1471. DOIhttps://doi.org/10.1134/S003602361611019X.

3. Tarasevich Yu.I. Stroenie i himiya poverhnosti sloistyh silikatov. Kiev: Nauk. dumka, 1988. 246 s.

4. Bel'chinskaya L.I., Khodosova N.A., Novikova L.A., Strel'nikova O.Yu., Roessner F., Petukhova G.A., Zhabin A.V. Regulation of sorption processes in natural nanoporous aluminosilicates. 2. Determination of the ratio bitween active sites // Protect. Met. Phys. Chem.Surf. 2016. Vol. 52, no. 4. P. 599-606. DOIhttps://doi.org/10.1134/S207020511604005.

5. Grevcev V.A., Lygina T.Z. Morfologicheskie i ctrukturnye osobennosti prirodnyh, aktivirovannyh i sintezirovannyh veschestv // Vestn. Kazan. tehnol. un-ta. 2010. № 8. S. 236-249.

6. Razgovorov P.B., Ignat'ev A.A., Abramov M.A., Nagornov R.S. Pererabotka alyumosilikatnogo syr'ya i otvalov stroitel'stva metropolitena v kompozicionnye sorbenty dlya ochistki vodnyh i maslosoderzhaschih sred // Umnye kompozity v stroitel'stve. 2020. T. 1, vyp. 1. S. 10-26. URL: http://comincon.ru/index.php/tor/issue/view/v1n1_2020.

7. Efendiev A.A. O kristallizacii voskov v rafinirovannom podsolnechnom masle // Maslozhir. prom-st'. 1994. № 5-6. S. 22-25.

8. Mihaylov G.G., Lonzinger T.M., Morozova A.G., Skotnikov V.A., Lonzinger A.V., Kutuev A.A. Vliyanie sostava i struktury prirodnyh alyumosilikatnyh materialov Chelyabinskoy oblasti na sorbcionnye svoystva // Vestn. Yuzhno-Ural. gos. un-ta. Ser. Metallurgiya. 2015. T. 15, № 4. S. 42-50. DOI:https://doi.org/10.14529/met150405.

9. Lygina T.Z., Mihaylova O.A., Hacrinov A.I, Konyuhova T.P. Tehnologii himicheskoy aktivacii neorganicheskih prirodnyh mineral'nyh sorbentov. Kazan': Kazan. gos. tehnol. un-t, 2009. 117 s.

10. Sharafiev D.R., Hacrinov A.I., Usmanov N.V., Kasymova G.I. Modificirovannye prirodnye adsorbenty dlya rafinacii rastitel'nyh masel // Vestn. Tehnol. un-ta. 2017. T. 20, № 18. S. 88-92.

11. Arfaoui S., Frini-Srasra N., Srasra E. Synthesis and characterization of hydroxy-chromium pillared bentonite // Surf. Eng. Appl. Electrochem. 2009. Vol. 45, no. 3. P. 239-245. DOIhttps://doi.org/10.3103/S1068375509030119.

12. Butman M.F., Ovchinnikov N.L., Arbuznikov V.V., Agafonov A.V. Sintez i svoystva Al pillarirovannogo montmorillonita prirodnogo proishozhdeniya // Izv. vuzov. Himiya i him. tehnologiya. 2012. T. 55, № 8. S. 73-77.

13. Ignatyev A.A., Razgovorov P.B., Nagornov R.S., Politaeva N.A., Mukhametova L.R., Ilyashenko S.B. Composite Aluminosilicate Materials for Sorption Extraction of Impurity Substances of Vegetable Oils // Resources. 2022. Vol. 11, no. 9. p. 1-13.

14. Razgovorov P.B., Sitanov S.V., Kozlov V.A. Izuchenie vzaimodeystviya nekotoryh zatravochnyh materialov i slozhnoefirnoy sostavlyayuschey voskopodobnyh veschestv // Izv. vuzov. Himiya i him. tehnologiya. 2002. T. 45, vyp. 1. S. 34-37.

Login or Create
* Forgot password?