Yaroslavl, Yaroslavl, Russian Federation
Yaroslavl, Yaroslavl, Russian Federation
Yaroslavl, Yaroslavl, Russian Federation
Yaroslavl State Technical University
Yaroslavl, Russian Federation
Yaroslavl, Yaroslavl, Russian Federation
graduate student
Yaroslavl, Yaroslavl, Russian Federation
UDC 547.572.1
During the research, by alkylation of benzene with hexanol-1 the mixture consisting of 60-65% 2-phenylhexane and 35-40% 3-phenylhexane was synthesised. The paper explores the promising but understudied process of this mixture aerobic liquid phase oxidation to corresponding hydroperoxides for further obtaining of higher ketones. As a result, the use of N-hydroxyphthalimide at this stage allows us to achieve technological conditions for mixture industrial implementation. The conversion of the phenylhexane mixture is more than 30% within 60 minutes of reaction with high selectivity of hydroperoxide formation.
Alkylation, oxidation, 2 phenylhexane, 3 phenylhexane
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