From Chemistry Towards Technology Step-By-Step From Chemistry Towards Technology Step-By-Step От химии к технологии шаг за шагом 2782-1900 82262 10.52957/27821900_2022_03_17 Научные статьи Scientific articles Научные статьи Extraction of copper ions by a sorbent based on flax fiber modified with L-arginine Извлечение ионов меди сорбентом на основе льняного волокна, модифицированного L-аргинином Никифорова Татьяна Евгеньевна Nokoforova Tatyana Evgenjevna tatianaenik@mail.ru

доктор химических наук;

doctor of chemical sciences;

 Вокурова Дарья Андреевна Vokurova Daria Andreevna fresh-limon@mail.ru Софронов Артемий Романович Sofronov Artemiy Romanovich artemijsofronov@gmail.com Ивановский государственный химико-технологический университет Ivanovo State University of Chemistry and Technology 23 09 2022 23 09 2022 3 3 17 26 01 07 2022 12 09 2022 https://chemintech.ru/en/nauka/article/82262/view

В данной работе исследован процесс извлечения ионов Cu(II) из водных растворов целлюлозосодержащими сорбентами: нативным и модифицированным L-аргинином льняным волокном. Экспериментальные кинетические кривые сорбции ионов меди обработаны в рамках моделей псевдо-первого и псевдо-второго порядков. Высокий коэффициент корреляции (0,99) был получен в случае использования модели кинетики псевдо-второго порядка. Результаты обработки изотерм сорбции согласно модели Ленгмюра. свидетельствуют о применимости данной модели для описания процесса сорбции ионов меди сорбентами целлюлозной природы. В результате проведения двухступенчатого химического модифицирования через стадию окисления льняного волокна периодатом натрия и последующего модифицирования L-аргинином получен новый сорбент, который может быть использован для очистки водных растворов от ионов тяжелых металлов. Приведены СЭМ-изображения и элементный анализ исходного и модифицированного образцов льняного волокна. Изменения, произошедшие в льняном волокне в ходе модификации, подтверждают ИК-спектры. Полученный сорбент по своим сорбционным характеристикам значительно превосходит нативное льняное волокно, о чем свидетельствуют значения предельной сорбционной емкости.

This paper studies the process of Cu(II) ions extraction from aqueous solutions by cellulose-containing sorbents: native and modified by L-arginine flax fiber. We processed the experimental kinetic curves of copper ion sorption by pseudo-first and pseudo-second order models and obtain a high correlation coefficient (0.99) when used a pseudo-second order kinetics model. The results of the treatment of the sorption isotherms according to the Langmuir model indicate the model capability for the description of the process of copper ions sorption by cellulose sorbents. As a result of two-stage chemical modification through the oxidation stage of linen fibre with sodium periodate and subsequent modification with L-arginine, we obtain a new sorbent, which can be used to purify aqueous solutions from heavy metal ions. The paper also presents SEM images and elemental analysis of original and modified flax fibre samples. The infrared spectra confirms the changes occurred in the linen fibre during modification. The obtained sorbent significantly surpasses the native linen fibre in its sorption characteristics, as evidenced by the values of the ultimate sorption capacity.

 льняное волокно модифицирование L-аргинин метапериодат натрия сорбция ионы Cu (II) flax fibre modification L-arginine sodium metaperiodate sorption Cu(II) ions Исследование проведено с использованием ресурсов Центра коллективного пользования научным оборудованием ИГХТУ (при поддержке Минобрнауки России, соглашение № 075-15-2021-671). Работа выполнена в рамках государственного задания на выполнение НИР. Тема № FZZW-2020-0010. This work was supported by Ivanovo State University of Chemistry and Technology, Ivanovo, Russia Centre for the Collective Use of Scientific Equipment (the Russian Ministry of Education and Science, Agreement No. 075-15-2021-671). The work was carried out within the framework of the state research assignment. Theme № FZZW-2020-0010.

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