From Chemistry Towards Technology Step-By-Step From Chemistry Towards Technology Step-By-Step От химии к технологии шаг за шагом 2782-1900 83146 10.52957/27821900_2020_01_150 Научные статьи Scientific articles Научные статьи Stability of complex silver(i) and copper(i) ion compounds with unsaturated hydrocarbons and ammonia Stability of complex silver(i) and copper(i) ion compounds with unsaturated hydrocarbons and ammonia Смирнова Елена Алексеевна Smirnova Elena Alekseevna

кандидат химических наук;

candidate of chemical sciences;

 Ярославский государственный технический университет Yaroslavl State Technical University 31 12 2020 31 12 2020 1 1 150 154 11 09 2020 15 10 2020 https://chemintech.ru/en/nauka/article/83146/view

The following research paper studies thermodynamics of complexing silver ion mixed complex compounds with 1,3-butadiene and ammonia in aqueous solutions. The study contains comparative analysis of stability of complex silver(I) and copper(I) ion compounds with ammonia and unsaturated hydrocarbons (2-methylpropene and 1,3-butadiene). It proves higher stability of complex silver(I) ions compared to hydrocarbon complexes. The results of the following study of complexing silver ion mixed complex compounds with 1,3-butadiene and ammonia in aqueous solutions are of interest for chemistry and engineering chemistry.

The following research paper studies thermodynamics of complexing silver ion mixed complex compounds with 1,3-butadiene and ammonia in aqueous solutions. The study contains comparative analysis of stability of complex silver(I) and copper(I) ion compounds with ammonia and unsaturated hydrocarbons (2-methylpropene and 1,3-butadiene). It proves higher stability of complex silver(I) ions compared to hydrocarbon complexes. The results of the following study of complexing silver ion mixed complex compounds with 1,3-butadiene and ammonia in aqueous solutions are of interest for chemistry and engineering chemistry.

 compounds stability silver(I) copper(I) thermodynamics unsaturated hydrocarbons ammonia.

Bernardo P.Di, Melchior A., Portanova R., Tolazzi M., Zanonato P.L. Complex formation of N-donor ligands with group 11 monovalent ions. Coordination Chemistry Reviews. 2008. Vol. 252. P. 1270–1285. DOI: 10.1016/j.ccr.2007.12.007. Bernardo P.Di, Melchior A., Portanova R., Tolazzi M., Zanonato P.L. Complex formation of N-donor ligands with group 11 monovalent ions. Coordination Chemistry Reviews. 2008. Vol. 252. P. 1270–1285. DOI: 10.1016/j.ccr.2007.12.007. Antolovich M., Lindoy L.F., Reimers J.R. Explanation of the anomalous complexation of silver (I) with ammonia in term of the poor affinity of the ion for water. Journal of Physical Chemistry A. 2004. Vol. 108. P. 8434-8438. DOI: 10.1021/jp0495545. Antolovich M., Lindoy L.F., Reimers J.R. Explanation of the anomalous complexation of silver (I) with ammonia in term of the poor affinity of the ion for water. Journal of Physical Chemistry A. 2004. Vol. 108. P. 8434-8438. DOI: 10.1021/jp0495545. Del Piero S., Fedele R., Melchior A., Portanova R. Solvation effects on the stability of silver(I) complexes with pyridine-containing ligands studied by thermodynamic and DFT methods. Inorg. Chem. 2007. Vol. 46. № 11. P. 4683–4691. DOI: org/10.1021/ic070124d. Del Piero S., Fedele R., Melchior A., Portanova R. Solvation effects on the stability of silver(I) complexes with pyridine-containing ligands studied by thermodynamic and DFT methods. Inorg. Chem. 2007. Vol. 46. № 11. P. 4683–4691. DOI: org/10.1021/ic070124d. Piero S.D., Melchior A., Menotti D., Tolazzi M., Dossing A. Solvent effect on the thermodynamics of Ag(I) coordination to tripodal polypyridine ligands. Journal of Thermal Analysis and Calorimetry. 2009. Vol. 97. № 3. P. 845-851. DOI: 10.1007/s10973-009-0341-8. Piero S.D., Melchior A., Menotti D., Tolazzi M., Dossing A. Solvent effect on the thermodynamics of Ag(I) coordination to tripodal polypyridine ligands. Journal of Thermal Analysis and Calorimetry. 2009. Vol. 97. № 3. P. 845-851. DOI: 10.1007/s10973-009-0341-8. Melchior A., Tolazzi M., Polese P., Zanonato P.L. Thermodynamics of complex formation of silver(I) with N-donor ligands in non-aqueous solvents. Journal of Thermal Analysis and Calorimetry. 2017. Vol. 130. №1. P. 461-469. DOI: 10.1007/s10973-017-6289-1. Melchior A., Tolazzi M., Polese P., Zanonato P.L. Thermodynamics of complex formation of silver(I) with N-donor ligands in non-aqueous solvents. Journal of Thermal Analysis and Calorimetry. 2017. Vol. 130. №1. P. 461-469. DOI: 10.1007/s10973-017-6289-1. Silver(I) complexes with long-chain diamines in non-aqueous solvents: Thermodynamic and modeling studies. Journal of Thermal Analysis and Calorimetry. 2019. Vol. 138. №5. P. 3257-3265. DOI: 10.1007/s10973-019-08725-4. Silver(I) complexes with long-chain diamines in non-aqueous solvents: Thermodynamic and modeling studies. Journal of Thermal Analysis and Calorimetry. 2019. Vol. 138. №5. P. 3257-3265. DOI: 10.1007/s10973-019-08725-4. Andreeva V.V., Buzanov G.A., Malinina E.A., Kuznetsov N.T., Vologzhanina A.V. Silver(I) and Copper(I) Complexation with Decachloro-Closo-Decaborate Anion. Crystals. 2020. Vol. 10. № 5, P. 389-392. DOI: org/10.3390/cryst10050389. Andreeva V.V., Buzanov G.A., Malinina E.A., Kuznetsov N.T., Vologzhanina A.V. Silver(I) and Copper(I) Complexation with Decachloro-Closo-Decaborate Anion. Crystals. 2020. Vol. 10. № 5, P. 389-392. DOI: org/10.3390/cryst10050389. Quaretti Martina, Porchia M., Tisato F., Trapananti A., Aquilanti G., Damjanovic M., Marchio L., Quaretti Marco, Tegoni M. Thermodynamic stability and structure in aqueous solution of the [Cu(PTA)4]+ complex (PTA =  aminophosphine 1,3,5 triaza 7. Journal of Inorganic Biochemistry. 2018. Vol. 188. P. 50-61. DOI: org/10.1016/j.jinorgbio. 2018.08.008. Quaretti Martina, Porchia M., Tisato F., Trapananti A., Aquilanti G., Damjanovic M., Marchio L., Quaretti Marco, Tegoni M. Thermodynamic stability and structure in aqueous solution of the [Cu(PTA)4]+ complex (PTA =  aminophosphine 1,3,5 triaza 7. Journal of Inorganic Biochemistry. 2018. Vol. 188. P. 50-61. DOI: org/10.1016/j.jinorgbio. 2018.08.008. Endrizzi F., Bernando P.Di, Zanonato P.L., Tisato F. Cu(I) and Ag(I) complex formation with the hydrophilic phosphine 1,3,5-triaza-osphadamantane in different ionic media. How to estimate the effect of a complexing medium. Dalton Transactions. 2017. Vol. 46. № 5. P. 1455-1466. DOI: 10.1039/c6dt04221j. Endrizzi F., Bernando P.Di, Zanonato P.L., Tisato F. Cu(I) and Ag(I) complex formation with the hydrophilic phosphine 1,3,5-triaza-osphadamantane in different ionic media. How to estimate the effect of a complexing medium. Dalton Transactions. 2017. Vol. 46. № 5. P. 1455-1466. DOI: 10.1039/c6dt04221j. Sahin N., Sahin-Bolukbasi S., Marsan H. Synthesis and antitumor activity of new silver(I)-N-heterocyclic carbene complexes. Journal of Coordination Chemistry. 2019. Vol. 72. P. 3602-3613. DOI: 10.1080/00958972.2019.1697808. Sahin N., Sahin-Bolukbasi S., Marsan H. Synthesis and antitumor activity of new silver(I)-N-heterocyclic carbene complexes. Journal of Coordination Chemistry. 2019. Vol. 72. P. 3602-3613. DOI: 10.1080/00958972.2019.1697808. Halim S.N.A., Nordin F.J., Razak M.R.M., Sofyan N.R.F. M., Halim S.N.A., Rajab N. F., Sarip R. Synthesis, characterization, and evaluation of silver(I) complexes with mixed-ligands of thiosemicarbazones and diphenyl(p-tolyl)phosphine as biological agents. Journal of Coordination Chemistry. 2019. Vol. 72. P. 879-893. DOI: 10.1080/00958972.2019.1577400. Halim S.N.A., Nordin F.J., Razak M.R.M., Sofyan N.R.F. M., Halim S.N.A., Rajab N. F., Sarip R. Synthesis, characterization, and evaluation of silver(I) complexes with mixed-ligands of thiosemicarbazones and diphenyl(p-tolyl)phosphine as biological agents. Journal of Coordination Chemistry. 2019. Vol. 72. P. 879-893. DOI: 10.1080/00958972.2019.1577400. Loh Y.L., Haziz U.F.M., Haque R.A., Amirul A.A., Aidda O.N., Razali M.R. The effect of short alkane bridges in stability of bisbenzimidazole-2-ylidene silver(I) complexes: synthesis, crystal structure and antibacterial activity. Journal of Coordination Chemistry. 2019. Vol. 72. P. 894-907. DOI: 10.1080/00958972.2019.1599109. Loh Y.L., Haziz U.F.M., Haque R.A., Amirul A.A., Aidda O.N., Razali M.R. The effect of short alkane bridges in stability of bisbenzimidazole-2-ylidene silver(I) complexes: synthesis, crystal structure and antibacterial activity. Journal of Coordination Chemistry. 2019. Vol. 72. P. 894-907. DOI: 10.1080/00958972.2019.1599109. Olejnikova A.L., Temkin O.N., Bogdanov M.I., Flid R.M. Termodynamics of the reactions of formation of the -complex of butadiene-1,3 with ion Cu+. Neftehimija, 1970, T. 10, no. 2, S. 195 (in Russian). Olejnikova A.L., Temkin O.N., Bogdanov M.I., Flid R.M. Termodynamics of the reactions of formation of the -complex of butadiene-1,3 with ion Cu+. Neftehimija, 1970, T. 10, no. 2, S. 195 (in Russian). Petrov A.N., Temkin O.N., Bogdanov M.I. Termodynamics of the reaction of formation of the -complex of 1,3-butadiene by the silver ion. Neftehimija. 1969. T.9. №5. S. 729 (in Russian). Petrov A.N., Temkin O.N., Bogdanov M.I. Termodynamics of the reaction of formation of the -complex of 1,3-butadiene by the silver ion. Neftehimija. 1969. T.9. №5. S. 729 (in Russian). Smirnova E.A., Bogdanov M.I. Investigation of the thermodynamics of the complexation of the silver ion with 2-methylpropene and ammonia in aqueous solutions. Zhurnal fizicheskoj himii. 1975. T. 49. № 8. S. 2153 (in Russian). Smirnova E.A., Bogdanov M.I. Investigation of the thermodynamics of the complexation of the silver ion with 2-methylpropene and ammonia in aqueous solutions. Zhurnal fizicheskoj himii. 1975. T. 49. № 8. S. 2153 (in Russian). Olejnikova A.L., Temkin O.N., Bogdanov M.I., Flid R.M. Thermodynamics of reactions of the formation of the -complex of propene and 2-methylpropene with the Cu+ ion. Zhurnal fizicheskoj himii. 1970. T.44. № 9. S.2256 (in Russian). Olejnikova A.L., Temkin O.N., Bogdanov M.I., Flid R.M. Thermodynamics of reactions of the formation of the -complex of propene and 2-methylpropene with the Cu+ ion. Zhurnal fizicheskoj himii. 1970. T.44. № 9. S.2256 (in Russian).