From Chemistry Towards Technology Step-By-Step From Chemistry Towards Technology Step-By-Step От химии к технологии шаг за шагом 2782-1900 83145 10.52957/27821900_2020_01_108 Научные статьи Scientific articles Научные статьи Corroles as aromatic analogs of corrinoids and vitamin b12: synthesis, structural features and macrocycle properties, perspectives of material chemistry on corrole basis Corroles as aromatic analogs of corrinoids and vitamin b12: synthesis, structural features and macrocycle properties, perspectives of material chemistry on corrole basis Каримов Дмитрий Рустамович Karimov Dmitry Rustamovich

кандидат химических наук;

candidate of chemical sciences;

 Березин Дмитрий Борисович Berezin Dmitry Borisovich

доктор химических наук;

doctor of chemical sciences;

 Томилова Ирина Константиновна Tomilova Irina Konstantinovna

доктор медицинских наук;

doctor of medical sciences;

 Ивановский государственный химико-технологический университет Ivanovo State University of Chemistry and Technology Ивановская государственная медицинская академия Ivanovo State Medical Academy 31 12 2020 31 12 2020 1 1 108 149 11 09 2020 15 10 2020 https://chemintech.ru/en/nauka/article/83145/view

The review deals with literature and own experimental data for synthesis, structural features, spectral, acid-basic and coordinating properties of aromatic macroheterocycles – corroles. Perspectives of practical application of these compounds are considered briefly. Relationship between corrole properties and its geometrical and π-electronic structure is demonstrated. It is shown that corroles have number of features and unique characteristics in despite of insignificant change of structure compared to the most studied class of macroheterocyclic compounds – porphyrins.

The review deals with literature and own experimental data for synthesis, structural features, spectral, acid-basic and coordinating properties of aromatic macroheterocycles – corroles. Perspectives of practical application of these compounds are considered briefly. Relationship between corrole properties and its geometrical and π-electronic structure is demonstrated. It is shown that corroles have number of features and unique characteristics in despite of insignificant change of structure compared to the most studied class of macroheterocyclic compounds – porphyrins.

 tetrapyrrolic macroheterocyclic compounds; porphyrins; corroles; synthesis; spectral characteristics; acid-basic and coordinating properties; metallocomplexes; catalysis; photodynamic therapy

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