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 <front>
  <journal-meta>
   <journal-id journal-id-type="publisher-id">From Chemistry Towards Technology Step-By-Step</journal-id>
   <journal-title-group>
    <journal-title xml:lang="en">From Chemistry Towards Technology Step-By-Step</journal-title>
    <trans-title-group xml:lang="ru">
     <trans-title>От химии к технологии шаг за шагом</trans-title>
    </trans-title-group>
   </journal-title-group>
   <issn publication-format="online">2782-1900</issn>
  </journal-meta>
  <article-meta>
   <article-id pub-id-type="publisher-id">83100</article-id>
   <article-id pub-id-type="doi">10.52957/27821900_2021_01_161</article-id>
   <article-categories>
    <subj-group subj-group-type="toc-heading" xml:lang="ru">
     <subject>Научные статьи</subject>
    </subj-group>
    <subj-group subj-group-type="toc-heading" xml:lang="en">
     <subject>Scientific articles</subject>
    </subj-group>
    <subj-group>
     <subject>Научные статьи</subject>
    </subj-group>
   </article-categories>
   <title-group>
    <article-title xml:lang="en">Obtaining magnetite recovery iron-containing waste</article-title>
    <trans-title-group xml:lang="ru">
     <trans-title>Obtaining magnetite recovery iron-containing waste</trans-title>
    </trans-title-group>
   </title-group>
   <contrib-group content-type="authors">
    <contrib contrib-type="author">
     <name-alternatives>
      <name xml:lang="ru">
       <surname>Калаева</surname>
       <given-names>Сахиба Зияддин кзы</given-names>
      </name>
      <name xml:lang="en">
       <surname>Kalayeva</surname>
       <given-names>Sahiba Ziyaddin kizi</given-names>
      </name>
     </name-alternatives>
     <email>kalaevasz@ystu.ru</email>
     <bio xml:lang="ru">
      <p>доктор технических наук;</p>
     </bio>
     <bio xml:lang="en">
      <p>doctor of technical sciences;</p>
     </bio>
     <xref ref-type="aff" rid="aff-1"/>
    </contrib>
    <contrib contrib-type="author">
     <name-alternatives>
      <name xml:lang="ru">
       <surname>Маркелова</surname>
       <given-names>Надежда Леонидовна</given-names>
      </name>
      <name xml:lang="en">
       <surname>Markelova</surname>
       <given-names>Nadezhda Leonidovna</given-names>
      </name>
     </name-alternatives>
     <bio xml:lang="ru">
      <p>кандидат технических наук;</p>
     </bio>
     <bio xml:lang="en">
      <p>candidate of technical sciences;</p>
     </bio>
     <xref ref-type="aff" rid="aff-1"/>
    </contrib>
    <contrib contrib-type="author">
     <name-alternatives>
      <name xml:lang="ru">
       <surname>Макаров</surname>
       <given-names>Владимир Михайлович</given-names>
      </name>
      <name xml:lang="en">
       <surname>Makarov</surname>
       <given-names>Vladimir Mihaylovich</given-names>
      </name>
     </name-alternatives>
     <bio xml:lang="ru">
      <p>доктор технических наук;</p>
     </bio>
     <bio xml:lang="en">
      <p>doctor of technical sciences;</p>
     </bio>
     <xref ref-type="aff" rid="aff-2"/>
    </contrib>
   </contrib-group>
   <aff-alternatives id="aff-1">
    <aff>
     <institution xml:lang="ru">Ярославский государственный технический университет</institution>
    </aff>
    <aff>
     <institution xml:lang="en">Yaroslavl State Technical University</institution>
    </aff>
   </aff-alternatives>
   <aff-alternatives id="aff-2">
    <aff>
     <institution xml:lang="ru">ООО &quot;Домен&quot;</institution>
     <city>Ярославль</city>
     <country>Россия</country>
    </aff>
    <aff>
     <institution xml:lang="en">ООО &quot;Домен&quot;</institution>
     <city>Yaroslavl</city>
     <country>Russian Federation</country>
    </aff>
   </aff-alternatives>
   <pub-date publication-format="print" date-type="pub" iso-8601-date="2021-03-23T00:00:00+03:00">
    <day>23</day>
    <month>03</month>
    <year>2021</year>
   </pub-date>
   <pub-date publication-format="electronic" date-type="pub" iso-8601-date="2021-03-23T00:00:00+03:00">
    <day>23</day>
    <month>03</month>
    <year>2021</year>
   </pub-date>
   <volume>2</volume>
   <issue>1</issue>
   <fpage>161</fpage>
   <lpage>166</lpage>
   <history>
    <date date-type="received" iso-8601-date="2021-01-19T00:00:00+03:00">
     <day>19</day>
     <month>01</month>
     <year>2021</year>
    </date>
    <date date-type="accepted" iso-8601-date="2021-03-22T00:00:00+03:00">
     <day>22</day>
     <month>03</month>
     <year>2021</year>
    </date>
   </history>
   <self-uri xlink:href="https://chemintech.ru/en/nauka/article/83100/view">https://chemintech.ru/en/nauka/article/83100/view</self-uri>
   <abstract xml:lang="ru">
    <p>Based on the analysis of the literature data, it is determined that as a result of the expanding directions of application of the magnetic fluid, more and more magnetite is required to obtain it. The most common method of obtaining magnetite by chemical condensation makes magnetic fluid very expensive, one liter of which is sold for more than 500 USD. To reduce its cost, the paper proposes the methods of high-temperature reduction of iron-containing wastes to magnetite, which are metallurgical dust caught by electrofilters. As a reducing agent the waste activated carbon and carbon black (soot) are used the codes of which are included in the Federal classification catalog of waste (FKKO) and reflect a significant amount of their formation. After mixing iron-containing waste, activated carbon waste and carbon black, they are gradually heated to a temperature of 900 °C. These conditions create the possibility of the appearance of ferrous iron ions, which, occupying vacant places in the crystal lattice of iron oxide (III), contribute to the formation of magnetite. The magnetite was identified by X-ray technique and evaluated by the indicator of saturation magnetization in comparison with the natural magnetite appeared to be almost identical. The resulting magnetites were dissolved in hydrochloric acid and precipitated with ammonium hydroxide. Repeated determination of saturation magnetization did not show any difference in its level. In the suspension of magnetite, a dispersant in the form of oleic acid and a dispersion medium – kerosene was introduced during heating and stirring. The saturation magnetization and stability of the obtained magnetic fluid satisfied its application for water purification from oil and oil products spill.</p>
   </abstract>
   <trans-abstract xml:lang="en">
    <p>Based on the analysis of the literature data, it is determined that as a result of the expanding directions of application of the magnetic fluid, more and more magnetite is required to obtain it. The most common method of obtaining magnetite by chemical condensation makes magnetic fluid very expensive, one liter of which is sold for more than 500 USD. To reduce its cost, the paper proposes the methods of high-temperature reduction of iron-containing wastes to magnetite, which are metallurgical dust caught by electrofilters. As a reducing agent the waste activated carbon and carbon black (soot) are used the codes of which are included in the Federal classification catalog of waste (FKKO) and reflect a significant amount of their formation. After mixing iron-containing waste, activated carbon waste and carbon black, they are gradually heated to a temperature of 900 °C. These conditions create the possibility of the appearance of ferrous iron ions, which, occupying vacant places in the crystal lattice of iron oxide (III), contribute to the formation of magnetite. The magnetite was identified by X-ray technique and evaluated by the indicator of saturation magnetization in comparison with the natural magnetite appeared to be almost identical. The resulting magnetites were dissolved in hydrochloric acid and precipitated with ammonium hydroxide. Repeated determination of saturation magnetization did not show any difference in its level. In the suspension of magnetite, a dispersant in the form of oleic acid and a dispersion medium – kerosene was introduced during heating and stirring. The saturation magnetization and stability of the obtained magnetic fluid satisfied its application for water purification from oil and oil products spill.</p>
   </trans-abstract>
   <kwd-group xml:lang="en">
    <kwd>magnetite</kwd>
    <kwd>metallurgical dust</kwd>
    <kwd>waste of carbon black</kwd>
    <kwd>sediment of water de-Ironing station</kwd>
    <kwd>magnetic liquid</kwd>
   </kwd-group>
  </article-meta>
 </front>
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  <p></p>
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  <ref-list>
   <ref id="B1">
    <label>1.</label>
    <citation-alternatives>
     <mixed-citation xml:lang="ru">Morozov N.A., Kazakov Yu.B. Nanodisperse magnetic fluids in engineering and technology. Ivanovo: ISEU, 2011. 264 p. (in Russian).</mixed-citation>
     <mixed-citation xml:lang="en">Morozov N.A., Kazakov Yu.B. Nanodisperse magnetic fluids in engineering and technology. Ivanovo: ISEU, 2011. 264 p. (in Russian).</mixed-citation>
    </citation-alternatives>
   </ref>
   <ref id="B2">
    <label>2.</label>
    <citation-alternatives>
     <mixed-citation xml:lang="ru">Gordeev B.A., Maslov G.V., Okhulkov S.N., Osmekhin A.N. On Developing a Magneto-rheological Transformer That Operates in Orthogonal Magnetic Fields. Journal of Machinery Manufacture and Reliability. 2014. V. 43. N 2. P. 99–103. DOI: 10.3103/S105261881402006X</mixed-citation>
     <mixed-citation xml:lang="en">Gordeev B.A., Maslov G.V., Okhulkov S.N., Osmekhin A.N. On Developing a Magneto-rheological Transformer That Operates in Orthogonal Magnetic Fields. Journal of Machinery Manufacture and Reliability. 2014. V. 43. N 2. P. 99–103. DOI: 10.3103/S105261881402006X</mixed-citation>
    </citation-alternatives>
   </ref>
   <ref id="B3">
    <label>3.</label>
    <citation-alternatives>
     <mixed-citation xml:lang="ru">Belyaev E.S., Ermolaev A.I., Titov E.Yu., Tumakov S.F. Magnetorheological fluids: technologies of creation and application. Nizhnii Novgorod: NSTU named after R.E. Alekseeva, 2017. 94 p. (in Russian).</mixed-citation>
     <mixed-citation xml:lang="en">Belyaev E.S., Ermolaev A.I., Titov E.Yu., Tumakov S.F. Magnetorheological fluids: technologies of creation and application. Nizhnii Novgorod: NSTU named after R.E. Alekseeva, 2017. 94 p. (in Russian).</mixed-citation>
    </citation-alternatives>
   </ref>
   <ref id="B4">
    <label>4.</label>
    <citation-alternatives>
     <mixed-citation xml:lang="ru">Khoang Ch.T., Yurmazova T.A., Vaitulevich E.A. Magnetite with modified surface for water treatment. Izvestiya Tomskogo politekhnicheskogo universiteta. Inzhiniring georesursov. 2019. V. 330. N 8. P. 163-172. DOI: 10.18799/24131830/2019/8/2222 (in Russian).</mixed-citation>
     <mixed-citation xml:lang="en">Khoang Ch.T., Yurmazova T.A., Vaitulevich E.A. Magnetite with modified surface for water treatment. Izvestiya Tomskogo politekhnicheskogo universiteta. Inzhiniring georesursov. 2019. V. 330. N 8. P. 163-172. DOI: 10.18799/24131830/2019/8/2222 (in Russian).</mixed-citation>
    </citation-alternatives>
   </ref>
   <ref id="B5">
    <label>5.</label>
    <citation-alternatives>
     <mixed-citation xml:lang="ru">Lebedev A.V., Lysenko S.N., Gileev V.G. The magnetic liquid stabilized with polymethylsiloxane remains liquid without carrier medium. Kolloidnyi zhurnal. 2020. V. 82. No. 3. P. 339-345. DOI: 10.31857/S0023291220030064 (in Russian).</mixed-citation>
     <mixed-citation xml:lang="en">Lebedev A.V., Lysenko S.N., Gileev V.G. The magnetic liquid stabilized with polymethylsiloxane remains liquid without carrier medium. Kolloidnyi zhurnal. 2020. V. 82. No. 3. P. 339-345. DOI: 10.31857/S0023291220030064 (in Russian).</mixed-citation>
    </citation-alternatives>
   </ref>
   <ref id="B6">
    <label>6.</label>
    <citation-alternatives>
     <mixed-citation xml:lang="ru">Pshenichnikov A.F., Elfimova E.A., Ivanov A.O. Magnetophoresis, Sedimentation, and Diffusion of Particles in Concentrated Magnetic Fluids. Journal of Chemical Physics. 2011. V. 134. N 18. P. 184508 DOI: 10.1063/1.3586806</mixed-citation>
     <mixed-citation xml:lang="en">Pshenichnikov A.F., Elfimova E.A., Ivanov A.O. Magnetophoresis, Sedimentation, and Diffusion of Particles in Concentrated Magnetic Fluids. Journal of Chemical Physics. 2011. V. 134. N 18. P. 184508 DOI: 10.1063/1.3586806</mixed-citation>
    </citation-alternatives>
   </ref>
   <ref id="B7">
    <label>7.</label>
    <citation-alternatives>
     <mixed-citation xml:lang="ru">Antonenko T.S., Brik A.B., Ponomar V.P., Dudchenko N.A. Conversion of weakly magnetic minerals (hematite, goethite) into magnetite in an aqueous medium of iron (II) salts. Mineralogichnii zhurnal. 2018. V. 40. N 2(196). P. 36-44. DOI: 10.15407/mineraljournal.40.02.036 (in Russian).</mixed-citation>
     <mixed-citation xml:lang="en">Antonenko T.S., Brik A.B., Ponomar V.P., Dudchenko N.A. Conversion of weakly magnetic minerals (hematite, goethite) into magnetite in an aqueous medium of iron (II) salts. Mineralogichnii zhurnal. 2018. V. 40. N 2(196). P. 36-44. DOI: 10.15407/mineraljournal.40.02.036 (in Russian).</mixed-citation>
    </citation-alternatives>
   </ref>
   <ref id="B8">
    <label>8.</label>
    <citation-alternatives>
     <mixed-citation xml:lang="ru">Kalaeva S.Z., Makarov V.M., Shipilin M.A., Bazhanova A.G., Zakharova I.N., Yamanin I.A., Ershova A.N. Synthesis and application of magnetic fluid. Fiziko-khimicheskie i prikladnye problemy magnitnykh dispersnykh nanosistem: Conference Proceedings. September 14-17 2009. Stavropol': SSU, 2009. P. 7-10 (in Russian).</mixed-citation>
     <mixed-citation xml:lang="en">Kalaeva S.Z., Makarov V.M., Shipilin M.A., Bazhanova A.G., Zakharova I.N., Yamanin I.A., Ershova A.N. Synthesis and application of magnetic fluid. Fiziko-khimicheskie i prikladnye problemy magnitnykh dispersnykh nanosistem: Conference Proceedings. September 14-17 2009. Stavropol': SSU, 2009. P. 7-10 (in Russian).</mixed-citation>
    </citation-alternatives>
   </ref>
   <ref id="B9">
    <label>9.</label>
    <citation-alternatives>
     <mixed-citation xml:lang="ru">Albagachiev A.Yu., Danilov V.D. Magnetic fluid in the regime of hydrodynamic lubrication of spherical surfaces. Vestnik Bryanskogo gosudarstvennogo tekhnicheskogo universiteta. 2016. N 3(51). P. 90-93. DOI: 10.12737/22017 (in Russian).</mixed-citation>
     <mixed-citation xml:lang="en">Albagachiev A.Yu., Danilov V.D. Magnetic fluid in the regime of hydrodynamic lubrication of spherical surfaces. Vestnik Bryanskogo gosudarstvennogo tekhnicheskogo universiteta. 2016. N 3(51). P. 90-93. DOI: 10.12737/22017 (in Russian).</mixed-citation>
    </citation-alternatives>
   </ref>
   <ref id="B10">
    <label>10.</label>
    <citation-alternatives>
     <mixed-citation xml:lang="ru">Kazakov Yu.B., Stradomskii Yu.I., Morozov N.A., Perminov S.M. Sealers based on nanodispersed magnetic fluids and their modeling. Editor: Yu.B. Kazakova. Ivanovo: ISEU, 2010. 180 p. (in Russian).</mixed-citation>
     <mixed-citation xml:lang="en">Kazakov Yu.B., Stradomskii Yu.I., Morozov N.A., Perminov S.M. Sealers based on nanodispersed magnetic fluids and their modeling. Editor: Yu.B. Kazakova. Ivanovo: ISEU, 2010. 180 p. (in Russian).</mixed-citation>
    </citation-alternatives>
   </ref>
   <ref id="B11">
    <label>11.</label>
    <citation-alternatives>
     <mixed-citation xml:lang="ru">Morozov N.A., Kazakov Yu.B. Nanodisperse magnetic liquids in engineering and technology. Ivanovo: ISEU, 2011. 264 p. (in Russian).</mixed-citation>
     <mixed-citation xml:lang="en">Morozov N.A., Kazakov Yu.B. Nanodisperse magnetic liquids in engineering and technology. Ivanovo: ISEU, 2011. 264 p. (in Russian).</mixed-citation>
    </citation-alternatives>
   </ref>
   <ref id="B12">
    <label>12.</label>
    <citation-alternatives>
     <mixed-citation xml:lang="ru">Pshenichnikov A.F., Lebedev A.V., Radionov A.V., Efremov D.V. Magnetic fluid for operation in strong gradient fields. Kolloidnyi zhurnal. 2015. V. 77. N 2. P. 207-213. DOI: 10.7868/S0023291215020159 (in Russian).</mixed-citation>
     <mixed-citation xml:lang="en">Pshenichnikov A.F., Lebedev A.V., Radionov A.V., Efremov D.V. Magnetic fluid for operation in strong gradient fields. Kolloidnyi zhurnal. 2015. V. 77. N 2. P. 207-213. DOI: 10.7868/S0023291215020159 (in Russian).</mixed-citation>
    </citation-alternatives>
   </ref>
   <ref id="B13">
    <label>13.</label>
    <citation-alternatives>
     <mixed-citation xml:lang="ru">Kurbatov A.A., Morozov N.A., Stradomskii Yu.I., Shchelykalov Yu.Ya. Modeling of magnetic fluid regeneration process from magnetized petroleum products. Vestnik IGEU. 2003. Iss. 1. P. 26-30 (in Russian).</mixed-citation>
     <mixed-citation xml:lang="en">Kurbatov A.A., Morozov N.A., Stradomskii Yu.I., Shchelykalov Yu.Ya. Modeling of magnetic fluid regeneration process from magnetized petroleum products. Vestnik IGEU. 2003. Iss. 1. P. 26-30 (in Russian).</mixed-citation>
    </citation-alternatives>
   </ref>
   <ref id="B14">
    <label>14.</label>
    <citation-alternatives>
     <mixed-citation xml:lang="ru">Solov'eva O.Yu., Kalaeva S.Z., Makarov V.M., Korotaeva T.A., Ershova A.N. Disposal of magnetized petroleum products in rubber compounds and rubbers. Ekologiya i promyshlennost' Rossii. 2010. N 12. P. 22-23 (in Russian).</mixed-citation>
     <mixed-citation xml:lang="en">Solov'eva O.Yu., Kalaeva S.Z., Makarov V.M., Korotaeva T.A., Ershova A.N. Disposal of magnetized petroleum products in rubber compounds and rubbers. Ekologiya i promyshlennost' Rossii. 2010. N 12. P. 22-23 (in Russian).</mixed-citation>
    </citation-alternatives>
   </ref>
   <ref id="B15">
    <label>15.</label>
    <citation-alternatives>
     <mixed-citation xml:lang="ru">Makarov V.M., Kalaeva S.Z., Markelova N.L., Tyukina L.A., Dubov A.Y. Production of nanodisperse magnetite for polymer compositions to be used for various purposes. Magnetohydrodynamics. 2018. V. 54. N 1-2. P. 141–145. DOI: 10.22364/mhd.54.1-2.25</mixed-citation>
     <mixed-citation xml:lang="en">Makarov V.M., Kalaeva S.Z., Markelova N.L., Tyukina L.A., Dubov A.Y. Production of nanodisperse magnetite for polymer compositions to be used for various purposes. Magnetohydrodynamics. 2018. V. 54. N 1-2. P. 141–145. DOI: 10.22364/mhd.54.1-2.25</mixed-citation>
    </citation-alternatives>
   </ref>
   <ref id="B16">
    <label>16.</label>
    <citation-alternatives>
     <mixed-citation xml:lang="ru">Ershova A.N., Kalaeva S.Z., Makarov V.M., Zakharova I.N., Gushchin A.G., Shipilin M.A., Shipilin A.M. Obtaining magnetic fluids for medical technologies. 14 Mezhdunarod. Plesskaya konf. po nanodispersnym magnitnym zhidkostyam, Conference Proceedings. Ples, Sept., 7-10, 2010. P. 270-273 (in Russian).</mixed-citation>
     <mixed-citation xml:lang="en">Ershova A.N., Kalaeva S.Z., Makarov V.M., Zakharova I.N., Gushchin A.G., Shipilin M.A., Shipilin A.M. Obtaining magnetic fluids for medical technologies. 14 Mezhdunarod. Plesskaya konf. po nanodispersnym magnitnym zhidkostyam, Conference Proceedings. Ples, Sept., 7-10, 2010. P. 270-273 (in Russian).</mixed-citation>
    </citation-alternatives>
   </ref>
   <ref id="B17">
    <label>17.</label>
    <citation-alternatives>
     <mixed-citation xml:lang="ru">Kalaeva S.Z., Ershova A.N., Gushchin A.G., Makarov V.M. New ways of obtaining magnetic fluids for innovative medical technologies. XVI Conference Tekhnologicheskoe obrazovanie kak faktor innovatsionnogo razvitiya strany, Conference Proceedings. October, 4-8, 2010. Yaroslavl: YSPU named after K.D. Ushinskiy, 2010. P. 276-277 (in Russian).</mixed-citation>
     <mixed-citation xml:lang="en">Kalaeva S.Z., Ershova A.N., Gushchin A.G., Makarov V.M. New ways of obtaining magnetic fluids for innovative medical technologies. XVI Conference Tekhnologicheskoe obrazovanie kak faktor innovatsionnogo razvitiya strany, Conference Proceedings. October, 4-8, 2010. Yaroslavl: YSPU named after K.D. Ushinskiy, 2010. P. 276-277 (in Russian).</mixed-citation>
    </citation-alternatives>
   </ref>
   <ref id="B18">
    <label>18.</label>
    <citation-alternatives>
     <mixed-citation xml:lang="ru">Makarov V.M., Kalaeva S.Z., Kruchina M.A., Markelova N.L., Zakharova I.N., Ezhov A.A., Shipilin A.M. Production of magnetite-containing composite based on iron hydroxide from underground waters to synthesize magnetic fluids. Magnetohydrodynamics. 2018. V. 54. N 1-2. P. 137–140. DOI: 10.22364/mhd.54.1-2.24</mixed-citation>
     <mixed-citation xml:lang="en">Makarov V.M., Kalaeva S.Z., Kruchina M.A., Markelova N.L., Zakharova I.N., Ezhov A.A., Shipilin A.M. Production of magnetite-containing composite based on iron hydroxide from underground waters to synthesize magnetic fluids. Magnetohydrodynamics. 2018. V. 54. N 1-2. P. 137–140. DOI: 10.22364/mhd.54.1-2.24</mixed-citation>
    </citation-alternatives>
   </ref>
  </ref-list>
 </back>
</article>
