From Chemistry Towards Technology Step-By-Step From Chemistry Towards Technology Step-By-Step От химии к технологии шаг за шагом 2782-1900 83096 10.52957/27821900_2021_01_126 Научные статьи Scientific articles Научные статьи State and solvation of water h/d isotopologues in aprotic dipolar organic media based on results of thermochemical investigations State and solvation of water h/d isotopologues in aprotic dipolar organic media based on results of thermochemical investigations Иванов Евгений Викторович Ivanov Evgeny Viktorovich evi@isc-ras.ru

кандидат химических наук;

candidate of chemical sciences;

 Иванова Надежда Геннадьевна Ivanova Nadezhda Gennadievna nadezhda.ing@gmail.com

кандидат химических наук;

candidate of chemical sciences;

 Институт химии растворов им. Г.А. Крестова Российской академии наук Institute of Solution Chemistry of G.A. Krestov of the Russian Academy of Sciences Ивановский государственный энергетический университет Ivanovo Power Engineering Institute 23 03 2021 23 03 2021 2 1 126 143 05 02 2021 10 03 2021 https://chemintech.ru/en/nauka/article/83096/view

Based on the analysis of thermochemical data on the study of solvation of H2O and D2O molecules and the state of them in aprotic dipolar organic media, being available in the literature including the results of own calorimetric measurements by the authors, three groups of solvents were identified in the given review. They differ in the nature of specific interaction with water H/D isotopologues. The first group consists of moderately electron-donating tetrahydrofuran (THF), para-dioxane (DO), and acetone (Ac), solvents whose hydrogen-bonds with the solute water are not much inferior in energy to those being formed between H2O or D2O molecules. The effects of heterocomponent H(D)-bond formation in the solvents of second group consisting of the predominantly electron-accepting propylene carbonate (PC), acetonitrile (AN), and nitromethane (NM) are largely caused by the availability of their donor-acceptor centers to interact with water isotopologue molecules. In this sense, PC corresponds in overall to the solvents from first group, while steric inconsistencies for the interaction of AN and, especially, NM with H2O or D2O molecules decrease appreciably the hydrogen-bonding contribution to forming the water-containing “solvation complex”. The process of solvation of H2O or D2O molecules in solvents of the third group, namely, in N,N-dimethylformamide (DMF), N,N-dimethylacetamide (DMA), hexamethylphosphotriamide (HMPT), and dimethylsulphoxide (DMSO), where electron-donating abilities are higher than that of water, on the contrary, is accompanied by the formation of energetically more stable heterocomponent H- or D-bonds, compared to those existing in the “unary” aqueous medium. It was found that D2O‒H2O isotope effects (IE) in the standard molar enthalpy of water solvation are in rather good correlation with the energy of hydrogen bonding between H2O and an aprotic dipolar solvent. The specified enthalpy-isotope effects of solvation are also correlated in overall with the half-sum of donor and acceptor numbers (according to Gutmann) relating to the aprotic dipolar organic media being compared. The possibility of plotting the correct dependence of IE in the standard molar enthalpy of water solvation in amides on the solvent structuredness parameter (according to Ohtaki) was illustrated, too.

Based on the analysis of thermochemical data on the study of solvation of H2O and D2O molecules and the state of them in aprotic dipolar organic media, being available in the literature including the results of own calorimetric measurements by the authors, three groups of solvents were identified in the given review. They differ in the nature of specific interaction with water H/D isotopologues. The first group consists of moderately electron-donating tetrahydrofuran (THF), para-dioxane (DO), and acetone (Ac), solvents whose hydrogen-bonds with the solute water are not much inferior in energy to those being formed between H2O or D2O molecules. The effects of heterocomponent H(D)-bond formation in the solvents of second group consisting of the predominantly electron-accepting propylene carbonate (PC), acetonitrile (AN), and nitromethane (NM) are largely caused by the availability of their donor-acceptor centers to interact with water isotopologue molecules. In this sense, PC corresponds in overall to the solvents from first group, while steric inconsistencies for the interaction of AN and, especially, NM with H2O or D2O molecules decrease appreciably the hydrogen-bonding contribution to forming the water-containing “solvation complex”. The process of solvation of H2O or D2O molecules in solvents of the third group, namely, in N,N-dimethylformamide (DMF), N,N-dimethylacetamide (DMA), hexamethylphosphotriamide (HMPT), and dimethylsulphoxide (DMSO), where electron-donating abilities are higher than that of water, on the contrary, is accompanied by the formation of energetically more stable heterocomponent H- or D-bonds, compared to those existing in the “unary” aqueous medium. It was found that D2O‒H2O isotope effects (IE) in the standard molar enthalpy of water solvation are in rather good correlation with the energy of hydrogen bonding between H2O and an aprotic dipolar solvent. The specified enthalpy-isotope effects of solvation are also correlated in overall with the half-sum of donor and acceptor numbers (according to Gutmann) relating to the aprotic dipolar organic media being compared. The possibility of plotting the correct dependence of IE in the standard molar enthalpy of water solvation in amides on the solvent structuredness parameter (according to Ohtaki) was illustrated, too.

 water H/D isotopologues aprotic dipolar organic solvents standard molar enthalpies of dissolution and solvation isotope effects hydrogen-bonding donor-acceptor properties

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