From Chemistry Towards Technology Step-By-Step From Chemistry Towards Technology Step-By-Step От химии к технологии шаг за шагом 2782-1900 82375 10.52957/27821900_2022_02_115 Научные статьи Scientific articles Научные статьи Adsorption treatment of wastewater from petroleum products with plasma treated vermiculite Adsorption treatment of wastewater from petroleum products with plasma treated vermiculite Гусев Григорий Игоревич Gusev Grigory Igorevich

кандидат химических наук;

candidate of chemical sciences;

 Гущин Андрей Андреевич Gushchin Andrey Andreevich a_guschin@bk.ru

кандидат химических наук;

candidate of chemical sciences;

 Гриневич Владимир Иванович Grinevich Vladimir Ivanovich grin@isuct.ru

доктор химических наук;

doctor of chemical sciences;

 Бабурина Екатерина Михайловна Baburina Ekaterina Mihaylovna Извекова Татьяна Валерьевна Izvekova Tatiana Valer'evna

кандидат химических наук;

candidate of chemical sciences;

 Ивановский государственный химико-технологический университет Ivanovo State University of Chemistry and Technology Ивановский государственный химико-технологический университет Иваново Россия Ивановский государственный химико-технологический университет Иваново Russian Federation 23 06 2022 23 06 2022 3 2 115 128 25 05 2022 17 06 2022 https://chemintech.ru/en/nauka/article/82375/view

The paper presents the results of studies of wastewater treatment processes from petroleum products using vermiculite before and after treatment in dielectric barrier discharge plasma. During the experiment we determined the time of reaching equilibrium in the heterophase system "sorbent - aqueous solution of petroleum products", is 30 min. The kinetic sorption curves are processed in first- and second-order linear coordinates. We found that the kinetics of petroleum product sorption by vermiculite is most adequately described by a second-order kinetics model, indicating an ion-exchange adsorption process. The article describes the processes of external and internal mass transfer of petroleum products in the presence of vermiculite obtained under different conditions. When treating the sorption kinetics in Boyd-Adamson coordinates we found that the adsorption process proceeds in an inward diffusion regime. Treatment of the sorbent, after use in the wastewater treatment process, in dielectric barrier discharge plasma leads to a slight decrease of sorption characteristics, but results in its regeneration. We studied the morphology of vermiculite obtained under different conditions. The sample is a micro-heterogeneous material with a particle size of 0.4-0.7 µm. The total pore volume obtained from the linear coordinates of the micropore volumetric filling theory is 0.21 cm3/g. All microphotographs reflect the characteristic morphology of the vermiculite mica packet. The results of the study of the sorption properties evaluated by the method of low-temperature inert gas adsorption made it possible to construct isotherms of adsorption/desorption of liquid nitrogen on the sorbent surface, the BET treatment of which showed that the specific surface area of the sorbent is 7 m2/g.

The paper presents the results of studies of wastewater treatment processes from petroleum products using vermiculite before and after treatment in dielectric barrier discharge plasma. During the experiment we determined the time of reaching equilibrium in the heterophase system "sorbent - aqueous solution of petroleum products", is 30 min. The kinetic sorption curves are processed in first- and second-order linear coordinates. We found that the kinetics of petroleum product sorption by vermiculite is most adequately described by a second-order kinetics model, indicating an ion-exchange adsorption process. The article describes the processes of external and internal mass transfer of petroleum products in the presence of vermiculite obtained under different conditions. When treating the sorption kinetics in Boyd-Adamson coordinates we found that the adsorption process proceeds in an inward diffusion regime. Treatment of the sorbent, after use in the wastewater treatment process, in dielectric barrier discharge plasma leads to a slight decrease of sorption characteristics, but results in its regeneration. We studied the morphology of vermiculite obtained under different conditions. The sample is a micro-heterogeneous material with a particle size of 0.4-0.7 µm. The total pore volume obtained from the linear coordinates of the micropore volumetric filling theory is 0.21 cm3/g. All microphotographs reflect the characteristic morphology of the vermiculite mica packet. The results of the study of the sorption properties evaluated by the method of low-temperature inert gas adsorption made it possible to construct isotherms of adsorption/desorption of liquid nitrogen on the sorbent surface, the BET treatment of which showed that the specific surface area of the sorbent is 7 m2/g.

 adsorption vermiculite petroleum products water treatment dielectric barrier discharge plasma The work to determine the properties of the adsorbent was performed within the framework of the state research assignment (Theme No. FZZW-2020-0010). This work on adsorbent surface treatment in dielectric barrier discharge plasma was performed within the framework of the RF President's Grant for Governmental Support of Young Russian Scientists - Candidate of Sciences (MK-3784.2022.1.3). The research was performed using the resources of the ISUCT Centre for the Collective Use of Scientific Equipment (supported by the Russian Ministry of Education and Science, Agreement No. 075-15-2021-671).

Gusev, G.I., Gushchin, A.A., Grinevich, V.I., Izvekova, T.V. & Sharonov, A.V. (2021) Effects of dielectric barrier discharge on diatomite contaminated with oil products. Sorbtsionnye i khromatograficheskie protsessy, 21(1), pp. 60-68. DOI: https://doi.org/10.17308/sorpchrom.2021.21/3220 (in Russian). Gusev, G.I., Gushchin, A.A., Grinevich, V.I., Izvekova, T.V. & Sharonov, A.V. (2021) Effects of dielectric barrier discharge on diatomite contaminated with oil products. Sorbtsionnye i khromatograficheskie protsessy, 21(1), pp. 60-68. DOI: https://doi.org/10.17308/sorpchrom.2021.21/3220 (in Russian). Gusev, G.I., Gushchin, A.A., Grinevich, V.A., Fillipov, D.V., Moskalenko, E.A. & Shil’ke, M.A. (2021) Adsorption of 2,4-dichlorophenol and phenol from aqueous solutions by silicate sorbent. Zhurnal fizicheskoj himii, 95(2), pp. 279-284. DOI: 10.31857/S0044453721020102 (in Russian). Gusev, G.I., Gushchin, A.A., Grinevich, V.A., Fillipov, D.V., Moskalenko, E.A. & Shil’ke, M.A. (2021) Adsorption of 2,4-dichlorophenol and phenol from aqueous solutions by silicate sorbent. Zhurnal fizicheskoj himii, 95(2), pp. 279-284. DOI: 10.31857/S0044453721020102 (in Russian). Haskelberg, M.B., Shiyan, L.N., Kornev, Ya.I., Galanov, A.I., Titova, E.N. & Devyanin, D.S. (2011) Improving the efficiency of oil products removal from waste waters. Vestn. Tomsk. Polytekhnich. Un-ta. Inzhiniring georesursov, 319(3), pp. 32-35 (in Russian). Haskelberg, M.B., Shiyan, L.N., Kornev, Ya.I., Galanov, A.I., Titova, E.N. & Devyanin, D.S. (2011) Improving the efficiency of oil products removal from waste waters. Vestn. Tomsk. Polytekhnich. Un-ta. Inzhiniring georesursov, 319(3), pp. 32-35 (in Russian). Mitryushkina, K.P. (1987) Protection of Nature: Guide. M.: Agropromizdat (in Russian). Mitryushkina, K.P. (1987) Protection of Nature: Guide. M.: Agropromizdat (in Russian). Smirnov, A.D. (1982) Sorption water purification. L.: Khimiya (in Russian). Smirnov, A.D. (1982) Sorption water purification. L.: Khimiya (in Russian). Kamenshchikov, F.A. & Bogomol’niy, E.I. (2003) Oil sorbents. Izhevsk: Institut Komputerrnykh Issledovaniy (in Russian). Kamenshchikov, F.A. & Bogomol’niy, E.I. (2003) Oil sorbents. Izhevsk: Institut Komputerrnykh Issledovaniy (in Russian). Sobgayda, N.A. (2011) Sorption materials for the purification of waste and natural waters from oil products. Vestn. Har'kov. nac. avtomobil.-dorozhn. un-ta, 52, pp. 120-124 (in Russian). Sobgayda, N.A. (2011) Sorption materials for the purification of waste and natural waters from oil products. Vestn. Har'kov. nac. avtomobil.-dorozhn. un-ta, 52, pp. 120-124 (in Russian). Zubkov, A.A., Bagrov, V.V., Kamrukov, A.S., Kostritsa, V.N. & Krylov, V.I. (2020) Natural sorbents and their use in wastewater treatment. Vodoochistka. Vodopodgotovka. Vodosnabzhenie, 2, pp. 36-44 (in Russian). Zubkov, A.A., Bagrov, V.V., Kamrukov, A.S., Kostritsa, V.N. & Krylov, V.I. (2020) Natural sorbents and their use in wastewater treatment. Vodoochistka. Vodopodgotovka. Vodosnabzhenie, 2, pp. 36-44 (in Russian). Komendantova, E.A. & Kvasha, D.Yu. (2017) Adsorption in water treatment. The potential of natural adsorbents. Sinergiya nauk, 11, p. 913 (in Russian). Komendantova, E.A. & Kvasha, D.Yu. (2017) Adsorption in water treatment. The potential of natural adsorbents. Sinergiya nauk, 11, p. 913 (in Russian). Alykov, N.M., Abuova, G.B., Menkeyev, O.A. & Zuy, N.K. (2009) Adsorption of organic substances from water by sorbent OPP-1. Estestvennye nauki, 1(26), pp. 11-17 (in Russian). Alykov, N.M., Abuova, G.B., Menkeyev, O.A. & Zuy, N.K. (2009) Adsorption of organic substances from water by sorbent OPP-1. Estestvennye nauki, 1(26), pp. 11-17 (in Russian). Faskhutdinova, Z.T., Shaikhiev, I.G. & Abdullin, I.Sh. (2014) Improving the efficiency of the method of cleaning oil-containing wastewater water by modified felt production waste. Vestn. Kazan. Tekhnologich. Un-ta, 17(21), pp. 220-222 (in Russian). Faskhutdinova, Z.T., Shaikhiev, I.G. & Abdullin, I.Sh. (2014) Improving the efficiency of the method of cleaning oil-containing wastewater water by modified felt production waste. Vestn. Kazan. Tekhnologich. Un-ta, 17(21), pp. 220-222 (in Russian). Cambiella, A., Ortea, E., Rios, G., Benito, J.M., Pazos, C. & Coca, J. (2006) Treatment of oil-in-water emulsions: performance of a sawdust bed filter. J. Hazard. Materials, 131(1–3), pp. 195. https://doi.org/10.1016/j.jhazmat.2005.09.023 Cambiella, A., Ortea, E., Rios, G., Benito, J.M., Pazos, C. & Coca, J. (2006) Treatment of oil-in-water emulsions: performance of a sawdust bed filter. J. Hazard. Materials, 131(1–3), pp. 195. https://doi.org/10.1016/j.jhazmat.2005.09.023 Melnikov, A.A., Gordina, N.E., Tyukanova, K.A., Gusev, G.I. Gushchin, A.A. & Rumyantsev, R.N. (2021) Synthesis of sorption systems based on mechano-chemically activated vermiculite. Izvestiya vysshikh uchebnykh zavedenii. Khimiya i khimicheskaya tekhnologiya, 64(8), pp. 63-71. DOI: https://doi.org/10.6060/ivkkt.20216408.6422 (in Russian). Melnikov, A.A., Gordina, N.E., Tyukanova, K.A., Gusev, G.I. Gushchin, A.A. & Rumyantsev, R.N. (2021) Synthesis of sorption systems based on mechano-chemically activated vermiculite. Izvestiya vysshikh uchebnykh zavedenii. Khimiya i khimicheskaya tekhnologiya, 64(8), pp. 63-71. DOI: https://doi.org/10.6060/ivkkt.20216408.6422 (in Russian). Ivanova, E.N., Alekhina, M.B. & Akhnazarova, S.L. (2012) Thermal activation of type X zeolites. Uspekhi v khimii i khimicheskoi tekhnologii, 26(8) (137), pp. 26-30 (in Russian). Ivanova, E.N., Alekhina, M.B. & Akhnazarova, S.L. (2012) Thermal activation of type X zeolites. Uspekhi v khimii i khimicheskoi tekhnologii, 26(8) (137), pp. 26-30 (in Russian). Rakhmonov O.K. (2020) The effect of ultrasonic sounding on the intensification of the adsorption cleaning process of paraffin. Universum: technical sciences, 6-2 (75), pp. 87-90 (in Russian). Rakhmonov O.K. (2020) The effect of ultrasonic sounding on the intensification of the adsorption cleaning process of paraffin. Universum: technical sciences, 6-2 (75), pp. 87-90 (in Russian). Nikiforova, T.E., Kozlov, V.A. & Odintsova, O.I. (2015) Regularities of copper (II) and nickel (III) ions distribution in heterophase system “water solution – modified flax fiber”. Rossiiskii khimicheskii zhurnal, 59(4), pp. 76-84. DOI: 10.6060/rcj (in Russian). Nikiforova, T.E., Kozlov, V.A. & Odintsova, O.I. (2015) Regularities of copper (II) and nickel (III) ions distribution in heterophase system “water solution – modified flax fiber”. Rossiiskii khimicheskii zhurnal, 59(4), pp. 76-84. DOI: 10.6060/rcj (in Russian). Losev, N.V., Nikiforova, T.E., Makarova, L.I. & Lipatova, I.M. (2017) Influence of mechanical activation on structure and sorption capacity of chitin. Fizikokhimiya poverkhnosti i zashchita materialov, 53(5), pp. 480 485. DOI: 10.1134 (in Russian). Losev, N.V., Nikiforova, T.E., Makarova, L.I. & Lipatova, I.M. (2017) Influence of mechanical activation on structure and sorption capacity of chitin. Fizikokhimiya poverkhnosti i zashchita materialov, 53(5), pp. 480 485. DOI: 10.1134 (in Russian). Gusev, G.I., Gushin, A.A., Grinevich, V.I., Osti, A.A., Izvekova, T.V. & Kvitkova, E.Yu. (2017) Regeneration of natural sorbents contam-inated with oil products in dielectric barrier discharge plasma. Izv. Vyssh. Uchebn. Zaved. Khim. Khim. Tekhnol., 60(6), pp. 72-76. DOI: 10.6060/tcct.2017606.5521 (in Russian). Gusev, G.I., Gushin, A.A., Grinevich, V.I., Osti, A.A., Izvekova, T.V. & Kvitkova, E.Yu. (2017) Regeneration of natural sorbents contam-inated with oil products in dielectric barrier discharge plasma. Izv. Vyssh. Uchebn. Zaved. Khim. Khim. Tekhnol., 60(6), pp. 72-76. DOI: 10.6060/tcct.2017606.5521 (in Russian). Shaikhiev, I.G., Nizamov, R.H., Abdullin, I.Sh. & Friedland, S.V. (2010) Modification of an alternative sorbent by plasma treatment to increase oil capacity and hydrophobicity. Zashchita okruzhayushchei sredy v neftegazovom komplekse, 4, pp. 24-27 (in Russian). Shaikhiev, I.G., Nizamov, R.H., Abdullin, I.Sh. & Friedland, S.V. (2010) Modification of an alternative sorbent by plasma treatment to increase oil capacity and hydrophobicity. Zashchita okruzhayushchei sredy v neftegazovom komplekse, 4, pp. 24-27 (in Russian). Adamson, A., Abidor, I.G. & Deryagin, B.V. (1979) Physical chemistry of surfaces. M.: Mir (in Russian). Adamson, A., Abidor, I.G. & Deryagin, B.V. (1979) Physical chemistry of surfaces. M.: Mir (in Russian). RF State Standard (GOST) 12597-67. Sorbents. Method for determining the mass fraction of water in active coals and catalysts based on them (in Russian). RF State Standard (GOST) 12597-67. Sorbents. Method for determining the mass fraction of water in active coals and catalysts based on them (in Russian). Goldstein, J., Newbury, D.E., Joy, D.C., Lyman, C.E., Echlin, P, Lifshin, E., Sawyer, L. & Michael, J.R. (2003) Scanning Electron Microscopy and X-ray Microanalysis. New York: Kluwer Academic. Plenum Publishers. Goldstein, J., Newbury, D.E., Joy, D.C., Lyman, C.E., Echlin, P, Lifshin, E., Sawyer, L. & Michael, J.R. (2003) Scanning Electron Microscopy and X-ray Microanalysis. New York: Kluwer Academic. Plenum Publishers. Melnikov, A.A., Gordina, N.E., Sinitsyn, A.P., Gusev, G.I., Gushchin, A.A. & Rumyantsev, R.N. (2022) Investigation of the influence of mechanochemical effects on the structure and properties of vermiculite sorbents. Journal of Solid State Chemistry, 306, pp. 122795. DOI: 10.1016/j.jssc.2021.122795. Melnikov, A.A., Gordina, N.E., Sinitsyn, A.P., Gusev, G.I., Gushchin, A.A. & Rumyantsev, R.N. (2022) Investigation of the influence of mechanochemical effects on the structure and properties of vermiculite sorbents. Journal of Solid State Chemistry, 306, pp. 122795. DOI: 10.1016/j.jssc.2021.122795. Guidelines for the measurement of the mass concentration of oil in the samples of drinking water and surface and under-ground water sources (PND F 14.1: 2: 4.129-98). M., 1998 (in Russian). Guidelines for the measurement of the mass concentration of oil in the samples of drinking water and surface and under-ground water sources (PND F 14.1: 2: 4.129-98). M., 1998 (in Russian). Bolshakov, G.F. (1986) Infrared spectra of saturated hydrocarbons. Part 1. Alkanes. Novosibirsk: Nauka (in Russian). Bolshakov, G.F. (1986) Infrared spectra of saturated hydrocarbons. Part 1. Alkanes. Novosibirsk: Nauka (in Russian). Kazakova, L.P. & Crane, S.E. (1978) Physico-chemical bases of oil production. M.: Chemistry (in Russian). Kazakova, L.P. & Crane, S.E. (1978) Physico-chemical bases of oil production. M.: Chemistry (in Russian). Yang, K., Wu, W., Jing, Q., Jiang, W. & Xing, B. (2010) Competitive adsorption of naphthalene with 2,4 dichlorophenol and 4-chloroaniline on multiwalled carbon nanotubes. Environmental science & technolog, 44(8), pp. 3021-3027. Yang, K., Wu, W., Jing, Q., Jiang, W. & Xing, B. (2010) Competitive adsorption of naphthalene with 2,4 dichlorophenol and 4-chloroaniline on multiwalled carbon nanotubes. Environmental science & technolog, 44(8), pp. 3021-3027. Zhang, Y., Jia, Y., Li, M. & Hou, L. (2018) Influence of the 2-methylimidazole/zinc nitrate hexahydrate molar ratio on the synthesis of zeolitic imidazolate framework-8 crystals at room temperature. Scientific Reports, 8(1), pp. 1-7. DOI:10.1038/s41598-018-28015-7 Zhang, Y., Jia, Y., Li, M. & Hou, L. (2018) Influence of the 2-methylimidazole/zinc nitrate hexahydrate molar ratio on the synthesis of zeolitic imidazolate framework-8 crystals at room temperature. Scientific Reports, 8(1), pp. 1-7. DOI:10.1038/s41598-018-28015-7 Goldberg, S. (2005) Equations and Models Describing Adsorption Processes in Soils. Soil Science Society of America, (8), 677 s. Goldberg, S. (2005) Equations and Models Describing Adsorption Processes in Soils. Soil Science Society of America, (8), 677 s. Gusev, G.I., Gushchin, A.A., Grinevich, V.I., Filippov, D.V. & Izvekova, T.V. (2018) Physical and chemical properties of sorbents used for wastewater purification from oil products. Izv. Vysh. Uchebn. Zaved. Khim. Khim. Tekhnol., 61(7), pp. 137-143. DOI: 10.6060/ivkkt.20186107.5686 (in Russian). Gusev, G.I., Gushchin, A.A., Grinevich, V.I., Filippov, D.V. & Izvekova, T.V. (2018) Physical and chemical properties of sorbents used for wastewater purification from oil products. Izv. Vysh. Uchebn. Zaved. Khim. Khim. Tekhnol., 61(7), pp. 137-143. DOI: 10.6060/ivkkt.20186107.5686 (in Russian). Gubkina, T.G., Belyaevsky, A.T. & Masloboev, V.A. (2011) Ways of producing hydrophobic oil sorbents by modifying the surface of vermiculite with organosiloxanes. Vestnik Murmanskogo gos. tekhn. un-ta, 14(4), pp. 767-773 (in Russian). Gubkina, T.G., Belyaevsky, A.T. & Masloboev, V.A. (2011) Ways of producing hydrophobic oil sorbents by modifying the surface of vermiculite with organosiloxanes. Vestnik Murmanskogo gos. tekhn. un-ta, 14(4), pp. 767-773 (in Russian).