From Chemistry Towards Technology Step-By-Step From Chemistry Towards Technology Step-By-Step От химии к технологии шаг за шагом 2782-1900 80842 10.52957/2782-1900-2024-5-1-8-32 Научные статьи Scientific articles Научные статьи Comparative description of the extraordinary phenomenon "thermally activated isobaric partial structure compaction" of water as a solute in some alkanols and alkylamines Сравнительная характеристика неординарного явления «термоактивируемого изобарического парциального уплотнения структуры» воды как растворенного вещества в некоторых алканолах и алкиламинах Иванов Евгений Викторович Ivanov Evgeny Viktorovich evi@isc-ras.ru

кандидат химических наук;

candidate of chemical sciences;

 Лебедева Елена Юрьевна Lebedeva Elena Yurievna eyl@isc-ras.ru

кандидат химических наук;

candidate of chemical sciences;

 Пакина Арина Алексеевна Pakina Arina Alekseevna arinapakina22@gmail.com Иванова Надежда Геннадьевна Ivanova Nadezhda Gennadievna nadezhda.ing@gmail.com

кандидат химических наук;

candidate of chemical sciences;

 Институт химии растворов им. Г.А. Крестова Российской академии наук Institute of Solution Chemistry of G.A. Krestov of the Russian Academy of Sciences Ивановский государственный химико-технологический университет Ivanovo State University of Chemistry and Technology Ивановский государственный энергетический университет Ivanovo Power Engineering Institute 23 03 2024 23 03 2024 5 1 8 32 06 02 2024 12 03 2024 https://chemintech.ru/en/nauka/article/80842/view

В обзоре обобщены имеющиеся в литературе сведения, включая опубликованные авторами результаты собственных прецизионных денсиметрических измерений, по исследованию необычного с физической точки зрения явления «термоактивируемого изобарического парциального уплотнения структуры» (ТИПУС) растворенной воды или ее т.н. «отрицательной парциальной молярной расширяемости» (ОПМР) в ряде органических растворителей. В качестве последних представлены амфипротонные гидроксилсодержащие среды трех спиртов: метилового (МС), третичных бутилового (ТБС) и амилового или пентилового (ТПС), а также протофильные среды двух аминов: трет-бутиламина (ТБА) и этилендиамина (ЭДА). Обсуждаемое явление ТИПУС, связанное c уменьшением стандартного (парциального при бесконечном разведении) объема сольватированной воды с ростом температуры, было обнаружено около полувека назад в алканольных растворах H2O и сравнительно недавно ‒ в водосодержащих средах алкиламинов. Однако до настоящего времени этот неординарный эффект пока еще не обрел своего физически обоснованного толкования, которое позволило бы прогнозировать возможность проявления ТИПУС в конкретно выбранной для исследования бинарной жидкофазной системе. Проведенный нами всесторонний анализ существующей на сегодняшний день информации по рассматриваемому вопросу позволил сделать несколько умозаключений касательно основных характеристик стандартного раствора H2O в органическом растворителе, благодаря которым возникают столь неординарные изменения в объеме образующегося сольватокомплекса воды под влиянием повышающейся температуры. Во-первых, энергетические параметры межмолекулярного взаимодействия (относительного сродства) вода ‒ растворитель заметно доминируют над таковыми при взаимодействии растворитель ‒ растворитель, и эти различия становятся все более выраженными с ростом температуры. Во-вторых, вследствие указанных различий, обнаруживается более высокий темп термического расширения структуры органического растворителя в объеме (inbulk), чем это имеет место в случае воздействия температуры на структурную упаковку образующегося смешанного молекулярного агрегата или сольватного комплекса воды. В третьих, различие в параметрах взаимодействия вода – растворитель и растворитель – растворитель находится в зависимости не только от протонодонорных/акцепторных свойств контактирующих в растворе молекул, но и от конфигурации структурной упаковки сольватирующей среды, обусловливающей характер стерических препятствий для образования H связей. С учетом этих обстоятельств установлено, что абсолютные величины упомянутых параметров относительного сродства при 298,15 К возрастают в ряду: МС << ЭДА ≈ ТБА < ТПС < ТБА, что может свидетельствовать об относительном усилении в указанной последовательности специфического взаимодействия (главным образом, через образование водородных связей) между молекулами воды и амфипротонного или протофильного растворителя. Иначе говоря, в обсуждаемых жидких средах алкиламинов (ТБА и ЭДА) и третично-изомерных алканолов (ТБС и ТПС) ‒ с наиболее выраженной основностью ‒ указанная выше разница в энергиях водородной связи растворитель‒растворитель и вода‒растворитель оказалась заметно большей, чем в структурной упаковке метанольного раствора воды, где способность компонентов к специфическим взаимодействиям вполне сопоставима.

This review summarises the data available in the literature. It also includes the authors' published results of precision densimetric measurements. The research concerns with the physically unusual phenomenon of "thermally activated isobaric partial densification of the structure" (TIPCS) of dissolved water, or its so-called "negative partial molar expandability" (NPEA) in several organic solvents. They contain amphiproton hydroxyl-containing media of three alcohols: methyl alcohol (MA), tertiary butyl alcohol (TBAlcohol), and amyl or pentyl alcohol (TPA), so asprotophilic media of two amines: tert butylamine (TBAmine) and ethylenediamine (EDA). The discussed TIPCS phenomenon, associated with a decrease in the standard (partial at infinite dilution) volume of solvated water with increasing temperature, was discovered about half a century ago in alkanol solutions of H2O and recently - in water-containing media of alkylamines. However, nowadays this extraordinary effect has not yet found its physically based interpretation. It allows ones to predict the possibility of TIPCS occurrence in the binary liquid-phase system specifically selected for the study. Our comprehensive data analysis allowed us to make several inferences regarding the main characteristics of a standard solution of H2O in an organic solvent. They cause extraordinary changes in the volume of the formed solvatocomplex of water under the influence of increasing temperature. Firstly, the energy parameters of the intermolecular interaction (relative affinity) water solvent noticeably dominate over those of the solvent-solvent interaction. Those differences become more evident with increasing temperature. Secondly, a higher rate of thermal expansion of the organic solvent structure in volume (inbulk) is found than influence of temperature on structural packing of the resulting mixed molecular aggregate or water solvates complex. Thirdly, the difference in the parameters of water-solvent and solvent-solvent interactions depends not only on the proton-donor/acceptor properties of the molecules contacting in solution, but also on the configuration of the structural packing of the solvating medium. It determines the nature of steric hindrances to the formation of H-bonds. Therefore, the absolute values of the mentioned parameters of relative affinity at 298.15 K increase in the series: MA << EDA ≈ TBAmine < TPAlcohol < TBAmine. It can indicate a relative strengthening of the specific interaction (mainly through the formation of hydrogen bonds) between the molecules of water and amphiprotonic or protophilic solvent in the above sequence. Indeed, difference in the solvent-solvent and water-solvent hydrogen bonding energies in the discussed liquid media of alkylamines (TBAmine and EDA) and tertiary isomeric alkanols (TBAlcohol and TPA) - with the most evident basicity - turned out to be noticeably larger than in the structural packing of water methanol solution. The ability of the components to specific interactions is quite comparable in those compounds.

 растворенная вода сольватация метанол трет-бутанол трет-пентанол трет-бутиламин этилендиамин стандартные молярные объемы отрицательная парциальная молярная расширяемость water solvation methanol tert-butanol tert-pentanol tert-butylamine ethylenediamine standard molar volumes negative partial molar expandability

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